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• W2148652079 abstract "The catalysis of peptide bond formation between two glycine molecules on H-FAU zeolite was computationally studied by the M08-HX density functional. Two reaction pathways, the concerted and the stepwise mechanism, starting from three differently adsorbed reactants, amino-bound, carboxyl-bound, and hydroxyl-bound, are studied. Adsorption energies, activation energies, and reaction energies, as well as the corresponding intrinsic rate constants were calculated. A comparison of the computed energetics of the various reaction paths for glycine indicates that the catalyzed reaction proceeds preferentially via the concerted reaction mechanism of the hydroxyl-bound configuration. This involves an eight-membered ring of the transition structure instead of the four-membered ring of the others. The step from the amino-bound configuration to glycylglycine is the rate-determining step of the concerted mechanism. It has an estimated activation energy of 51.2 kcal mol(-1). Although the catalytic reaction can also occur via the stepwise reaction mechanism, this path is not favored." @default.
• W2148652079 created "2016-06-24" @default.
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• W2148652079 date "2011-06-22" @default.
• W2148652079 modified "2023-10-17" @default.
• W2148652079 title "Glycine Peptide Bond Formation Catalyzed by Faujasite" @default.
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• W2148652079 cites W1972276720 @default.
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• W2148652079 cites W1980516378 @default.
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• W2148652079 cites W1985732802 @default.
• W2148652079 cites W1986460352 @default.
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• W2148652079 doi "https://doi.org/10.1002/cphc.201100047" @default.
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