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- W2148659800 abstract "Luminescence of NdIII in an organic solvent having C−H bonds was achieved for the first time by complexing NdIII with long-chain perfluoroalkylated ligands such as bis(perfluorooctylsulfonyl)aminate (pos). The complex [Nd(pos)3] gave an emission quantum yield of 3.0±0.5 % in undeuterated acetone. The bulky pos ligands suppress the excitation of C−H vibrations, energy migration at diffusional collision, and the coordination of acetone molecules (see picture) to the NdIII center, which otherwise quench the luminescence." @default.
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- W2148659800 date "2000-01-17" @default.
- W2148659800 modified "2023-10-16" @default.
- W2148659800 title "Luminescence of Novel Neodymium Sulfonylaminate Complexes in Organic Media" @default.
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- W2148659800 doi "https://doi.org/10.1002/(sici)1521-3773(20000117)39:2<357::aid-anie357>3.0.co;2-m" @default.
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