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- W2148781222 abstract "The first metal-free catalytic hydroboration of carbonyl derivatives has been developed in which a catalytic amount of 1,3,2-diazaphospholene effectively promotes a hydroboration reaction of aliphatic and aromatic aldehydes and ketones. The reaction mechanism involves the cleavage of both the PO bond of the alkoxyphosphine intermediate and the BH bond of pinacolborane as well as the formation of PH and BO bonds. Thus, the reaction proceeds through a non-metal σ-bond metathesis. Kinetic and computational studies suggest that the σ-bond metathesis occurred in a stepwise but nearly concerted manner." @default.
- W2148781222 created "2016-06-24" @default.
- W2148781222 creator A5048588199 @default.
- W2148781222 creator A5079744299 @default.
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- W2148781222 date "2014-11-05" @default.
- W2148781222 modified "2023-09-27" @default.
- W2148781222 title "Metal‐Free σ‐Bond Metathesis in 1,3,2‐Diazaphospholene‐Catalyzed Hydroboration of Carbonyl Compounds" @default.
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- W2148781222 doi "https://doi.org/10.1002/anie.201408760" @default.
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