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- W2148894751 abstract "A 1,1′ bis(diphenylphosphino ferrocene)dioxide complex of uranyl nitrate was synthesized and characterized by IR, 1H and 31P{1H} NMR spectroscopic and X-ray diffraction methods. The structure of the compound shows that the uranium atom is surrounded by eight oxygen atoms in a hexagonal bi-pyramidal geometry. Two oxygen atoms from 1,1′ bis(diphenylphosphino ferrocene)dioxide ligand and four oxygen atoms from the nitrate groups form a planar hexagon. The two uranyl oxygen atoms occupy the axial position. The 1,1′ bis(diphenylphosphino ferrocene)dioxide ligand acts as a bidentate chelating ligand with a bite angle of 71.56(8)° around the uranium(VI) atom, which is much smaller in value compare to any of the previously reported values (90.1°–154.0°) for this ligand." @default.
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- W2148894751 date "2010-06-01" @default.
- W2148894751 modified "2023-10-18" @default.
- W2148894751 title "Synthesis, characterization and molecular structure of 1,1′ bis(diphenylphosphino ferrocene)dioxide complex of uranyl nitrate" @default.
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- W2148894751 doi "https://doi.org/10.1016/j.ica.2010.03.032" @default.
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