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- W2148974278 abstract "Electron paramagnetic resonance (EPR) and optical absorption spectra of copper ions in xLiF-(50-x)Li 2 O-20SrO-30Bi 2 O 3 glass system have been studied. MDSC studies showed that the glass transition temperature decreases with LiF content. Optical absorption spectra of the pure glasses reveled that the cut off wave length increased and optical band gap energy decreased with increase in LiF content. EPR spectra of all the glass samples exhibit resonance signals characteristic of Cu 2+ ions. The Cu 2+ ions are in well-defined axial sites but subjected to small distortion leading to the broadening of the spectra. The spin-Hamiltonian parameter values indicate that the ground state of Cu 2+ is d x2 y2 and the site symmetry around Cu 2+ ions is tetragonally distorted octahedral. The optical absorption spectra exhibited a broad band corresponding to the d-d transition bands of Cu 2+ ion. By correlating EPR and optical absorption data, the bond parameters are evaluated from various techniques." @default.
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- W2148974278 date "2013-01-01" @default.
- W2148974278 modified "2023-10-16" @default.
- W2148974278 title "SYNTHESIS AND SPECTROSCOPY OF SOME QUATERNARY OXYFLUORIDE GLASSES DOPPED WITH COPPER" @default.
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- W2148974278 doi "https://doi.org/10.1142/s2010194513010246" @default.
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