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• W2148996844 abstract "Three new ruthenium(ii) polypyridyl complexes, [Ru(phen)2(Hecip)]2+ (1), [Ru(phen)(Hecip)2]2+ (2), and [Ru(Hecip)3]2+ (3) complexes (phen = 1,10-phenanthroline, Hecip = N-ethyl-4-([1,10]-phenanthroline[5,6–f]imidazol-2-yl)carbazole) were synthesized and characterized by ES-MS, 1H NMR spectroscopy, elemental analysis, and cyclic voltammetry. The emission spectra of complexes were measured both at room temperature and at 77 K in a 4/1 (v/v) EtOH/MeOH matrix. All three complexes display luminescence properties which are close to that featured by the parent [Ru(phen)3]2+ species. The pH effects on the UV-vis and emission spectra of RuII complexes were also studied, and complexes 1, 2, and 3 were found to act as ‘on–off’ luminescent pH switches with maximum on–off ratios of 17, 230, and 90, respectively." @default.
• W2148996844 created "2016-06-24" @default.
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• W2148996844 date "2010-01-01" @default.
• W2148996844 modified "2023-09-26" @default.
• W2148996844 title "Synthesis, Characterization, and Acid - Base Properties of Ruthenium(II) Complexes Containing N-ethyl-4-([1,10]-phenanthroline[5,6 - f]imidazol-2-yl)carbazole" @default.
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• W2148996844 doi "https://doi.org/10.1071/ch09565" @default.
• W2148996844 hasPublicationYear "2010" @default.
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