Matches in SemOpenAlex for { <https://semopenalex.org/work/W2149016980> ?p ?o ?g. }
Showing items 1 to 68 of
68
with 100 items per page.
- W2149016980 endingPage "93" @default.
- W2149016980 startingPage "85" @default.
- W2149016980 abstract "Abstract The thermodynamics of Ru(III)-EDTA catalyzed oxidation of cyclohexane to cyclohexanol and of cyclohexanol to cyclohexanone by molecular oxygen in acidic medium has been investigated in the temperature range 288–318 K, μ = 0.1 M KNO 3 in a 1:1 water:1,4-dioxane mixture (v/v). The dependence of the rate of oxidation on factors such as temperature (288–318 K), catalyst, substrates, molecular oxygen concentrations and pH was studied. The order of the reaction with respect to the concentrations of substrate and catalyst is unity. The dependence in molecular oxygen was found to be one-half and zero for the oxidations of cyclohexane and cyclohexanol, respectively. No dependence on [H + ] was observed for oxidation of cyclohexane. The rate of oxidation of cyclohexanol is inversely proportional to the hydrogen ion concentration. The thermodynamic parameters corresponding to equilibrium constants and activation parameters corresponding to rate constants were computed. The mechanisms proposed on the basis of the kinetic data are discussed in terms of thermodynamic stability and reactivity. The activation energy for the oxidation of cyclohexane is 7.3 kcal mol −1 higher than that of cyclohexanol. Thermodynamic factors are more favourable for the oxidation of cyclohexanol, which proceeds by a rate higher than that of cyclohexane." @default.
- W2149016980 created "2016-06-24" @default.
- W2149016980 creator A5042951757 @default.
- W2149016980 creator A5056012165 @default.
- W2149016980 date "1988-02-01" @default.
- W2149016980 modified "2023-09-27" @default.
- W2149016980 title "Thermodynamics of Ru(III)-edta catalyzed oxidation of saturated organic compounds by molecular oxygen" @default.
- W2149016980 cites W1978365821 @default.
- W2149016980 cites W1979299908 @default.
- W2149016980 cites W1986148181 @default.
- W2149016980 cites W1991272855 @default.
- W2149016980 cites W1992413871 @default.
- W2149016980 cites W1996341707 @default.
- W2149016980 cites W2032442204 @default.
- W2149016980 cites W2055508803 @default.
- W2149016980 cites W2074723598 @default.
- W2149016980 cites W2077471472 @default.
- W2149016980 cites W2082094549 @default.
- W2149016980 cites W2090159707 @default.
- W2149016980 cites W2091863683 @default.
- W2149016980 cites W2107873038 @default.
- W2149016980 cites W2117279891 @default.
- W2149016980 cites W2151588125 @default.
- W2149016980 cites W3005239982 @default.
- W2149016980 cites W3137651052 @default.
- W2149016980 cites W3138113620 @default.
- W2149016980 doi "https://doi.org/10.1016/0304-5102(88)80080-4" @default.
- W2149016980 hasPublicationYear "1988" @default.
- W2149016980 type Work @default.
- W2149016980 sameAs 2149016980 @default.
- W2149016980 citedByCount "27" @default.
- W2149016980 countsByYear W21490169802012 @default.
- W2149016980 crossrefType "journal-article" @default.
- W2149016980 hasAuthorship W2149016980A5042951757 @default.
- W2149016980 hasAuthorship W2149016980A5056012165 @default.
- W2149016980 hasConcept C161790260 @default.
- W2149016980 hasConcept C178790620 @default.
- W2149016980 hasConcept C179104552 @default.
- W2149016980 hasConcept C185592680 @default.
- W2149016980 hasConcept C2992086430 @default.
- W2149016980 hasConcept C540031477 @default.
- W2149016980 hasConceptScore W2149016980C161790260 @default.
- W2149016980 hasConceptScore W2149016980C178790620 @default.
- W2149016980 hasConceptScore W2149016980C179104552 @default.
- W2149016980 hasConceptScore W2149016980C185592680 @default.
- W2149016980 hasConceptScore W2149016980C2992086430 @default.
- W2149016980 hasConceptScore W2149016980C540031477 @default.
- W2149016980 hasIssue "1" @default.
- W2149016980 hasLocation W21490169801 @default.
- W2149016980 hasOpenAccess W2149016980 @default.
- W2149016980 hasPrimaryLocation W21490169801 @default.
- W2149016980 hasRelatedWork W2005854381 @default.
- W2149016980 hasRelatedWork W2046536769 @default.
- W2149016980 hasRelatedWork W2073133680 @default.
- W2149016980 hasRelatedWork W2317717775 @default.
- W2149016980 hasRelatedWork W2352284304 @default.
- W2149016980 hasRelatedWork W2377872675 @default.
- W2149016980 hasRelatedWork W2949679872 @default.
- W2149016980 hasRelatedWork W3039791815 @default.
- W2149016980 hasRelatedWork W758049092 @default.
- W2149016980 hasRelatedWork W2094722130 @default.
- W2149016980 hasVolume "44" @default.
- W2149016980 isParatext "false" @default.
- W2149016980 isRetracted "false" @default.
- W2149016980 magId "2149016980" @default.
- W2149016980 workType "article" @default.