FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W2149028163> ?p ?o ?g. }

• W2149028163 endingPage "390" @default.
• W2149028163 startingPage "379" @default.
• W2149028163 abstract "The speciation of arsenic (III) and (V) in aqueous acidic and basic solutions at ambient conditions, and of arsenic (V) in acidic solutions at 270 bars from 30 to 300 degreesC was investigated using in situ X-Ray Absorption Spectroscopy (XAS). Both Extended X-Ray Absorption Fine Structure (EXAFS) analysis and X-Ray Absorption Near Edge Structure (XANES) ab initio calculations were used to determine the structure of dominant arsenic species in solution. At ambient conditions, the deprotonation of AsIII(OH)3 and AsVO(OH)3 species with increasing pH is demonstrated by analysis of their XANES signals, in agreement with available arsenious and arsenic acid dissociation constants. In basic conditions, the dominant species is a deprotonated form of the As(OH)3 acid, with a very similar symmetry. The speciation of AsV in acidic hydrothermal fluids is dominated by the AsVO(OH)3 complex over a wide temperature and pressure range, to at least 300 degreesC and 300 bars. The first-shell As structure in the AsVO(OH)3 species and its deprotonated forms is found to be a distorted tetrahedron, similar to the base AsO4 unit of Na2HAsO4middle dot7H2O(s). This work demonstrates new capabilities of XAS coupled with molecular modelling to decipher deprotonation reactions that affect mineral solubilities and chemical elements mobility in aqueous crustal fluids." @default.
• W2149028163 created "2016-06-24" @default.
• W2149028163 creator A5033482117 @default.
• W2149028163 creator A5038595632 @default.
• W2149028163 creator A5050035487 @default.
• W2149028163 date "2011-07-13" @default.
• W2149028163 modified "2023-10-16" @default.
• W2149028163 title "Speciation of AsIII and AsV in hydrothermal fluids by in situ X-ray absorption spectroscopy" @default.
• W2149028163 cites W1516461961 @default.
• W2149028163 cites W1963633087 @default.
• W2149028163 cites W1963786658 @default.
• W2149028163 cites W1969051824 @default.
• W2149028163 cites W1974254794 @default.
• W2149028163 cites W1976076519 @default.
• W2149028163 cites W1988449517 @default.
• W2149028163 cites W1989514260 @default.
• W2149028163 cites W1989562946 @default.
• W2149028163 cites W199028227 @default.
• W2149028163 cites W1992086733 @default.
• W2149028163 cites W2000436896 @default.
• W2149028163 cites W2006994720 @default.
• W2149028163 cites W2016249727 @default.
• W2149028163 cites W2024832557 @default.
• W2149028163 cites W2033034088 @default.
• W2149028163 cites W2035175848 @default.
• W2149028163 cites W2037935218 @default.
• W2149028163 cites W2047851978 @default.
• W2149028163 cites W2050238167 @default.
• W2149028163 cites W2058604980 @default.
• W2149028163 cites W2061734145 @default.
• W2149028163 cites W2062468006 @default.
• W2149028163 cites W2066479861 @default.
• W2149028163 cites W2070227796 @default.
• W2149028163 cites W2074895963 @default.
• W2149028163 cites W2088512861 @default.
• W2149028163 cites W2099400868 @default.
• W2149028163 cites W2120507689 @default.
• W2149028163 cites W2121631713 @default.
• W2149028163 cites W2155665127 @default.
• W2149028163 cites W2236561874 @default.
• W2149028163 cites W2302669664 @default.
• W2149028163 cites W2312544977 @default.
• W2149028163 cites W341438757 @default.
• W2149028163 doi "https://doi.org/10.1127/0935-1221/2011/0023-2104" @default.
• W2149028163 hasPublicationYear "2011" @default.
• W2149028163 type Work @default.
• W2149028163 sameAs 2149028163 @default.
• W2149028163 citedByCount "16" @default.
• W2149028163 countsByYear W21490281632012 @default.
• W2149028163 countsByYear W21490281632013 @default.
• W2149028163 countsByYear W21490281632014 @default.
• W2149028163 countsByYear W21490281632015 @default.
• W2149028163 countsByYear W21490281632016 @default.
• W2149028163 countsByYear W21490281632018 @default.
• W2149028163 countsByYear W21490281632020 @default.
• W2149028163 countsByYear W21490281632022 @default.
• W2149028163 crossrefType "journal-article" @default.
• W2149028163 hasAuthorship W2149028163A5033482117 @default.
• W2149028163 hasAuthorship W2149028163A5038595632 @default.
• W2149028163 hasAuthorship W2149028163A5050035487 @default.
• W2149028163 hasConcept C107872376 @default.
• W2149028163 hasConcept C110715899 @default.
• W2149028163 hasConcept C113196181 @default.
• W2149028163 hasConcept C119824511 @default.
• W2149028163 hasConcept C120665830 @default.
• W2149028163 hasConcept C121332964 @default.
• W2149028163 hasConcept C125287762 @default.
• W2149028163 hasConcept C127313418 @default.
• W2149028163 hasConcept C127413603 @default.
• W2149028163 hasConcept C156622251 @default.
• W2149028163 hasConcept C159985019 @default.
• W2149028163 hasConcept C17409809 @default.
• W2149028163 hasConcept C178790620 @default.
• W2149028163 hasConcept C185592680 @default.
• W2149028163 hasConcept C18903297 @default.
• W2149028163 hasConcept C192562407 @default.
• W2149028163 hasConcept C199289684 @default.
• W2149028163 hasConcept C2776838516 @default.
• W2149028163 hasConcept C2777822432 @default.
• W2149028163 hasConcept C32891209 @default.
• W2149028163 hasConcept C42360764 @default.
• W2149028163 hasConcept C62284982 @default.
• W2149028163 hasConcept C62520636 @default.
• W2149028163 hasConcept C86803240 @default.
• W2149028163 hasConceptScore W2149028163C107872376 @default.
• W2149028163 hasConceptScore W2149028163C110715899 @default.
• W2149028163 hasConceptScore W2149028163C113196181 @default.
• W2149028163 hasConceptScore W2149028163C119824511 @default.
• W2149028163 hasConceptScore W2149028163C120665830 @default.
• W2149028163 hasConceptScore W2149028163C121332964 @default.
• W2149028163 hasConceptScore W2149028163C125287762 @default.
• W2149028163 hasConceptScore W2149028163C127313418 @default.
• W2149028163 hasConceptScore W2149028163C127413603 @default.
• W2149028163 hasConceptScore W2149028163C156622251 @default.
• W2149028163 hasConceptScore W2149028163C159985019 @default.
• W2149028163 hasConceptScore W2149028163C17409809 @default.
• W2149028163 hasConceptScore W2149028163C178790620 @default.
• W2149028163 hasConceptScore W2149028163C185592680 @default.

• next