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- W2149087865 abstract "Abstract In contrast to olefin complexes, their congeners of heavier elements display various coordination modes, and their complexes may be present as bis(metallylene) complexes, with side‐on coordination, as metallacyclopropanes, or as π complexes. In the course of our studies on the reactivity of dilithiostannoles towards transition‐metal reagents, three‐membered TiSn 2 and six‐membered Ti 2 Sn 4 ring complexes were obtained. According to its geometric parameters, NMR analysis, and theoretical calculations, the TiSn 2 complex cannot be categorized into any of these previously described bonding modes. Therefore, a novel resonance structure has been proposed for a complex that has a delocalized σ‐orbital over the TiSn 2 ring to understand its electronic structure. The mechanism for the formation of the Ti 2 Sn 4 ring complex and its EPR spectrum are also discussed." @default.
- W2149087865 created "2016-06-24" @default.
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- W2149087865 date "2013-11-28" @default.
- W2149087865 modified "2023-10-18" @default.
- W2149087865 title "Diversity of the Structures in a Distannene Complex and its Reduction to Generate a Six-Membered Ti<sub>2</sub>Sn<sub>4</sub>Ring Complex" @default.
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- W2149087865 doi "https://doi.org/10.1002/anie.201308565" @default.
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