FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W2149128236> ?p ?o ?g. }

• W2149128236 endingPage "5886" @default.
• W2149128236 startingPage "5879" @default.
• W2149128236 abstract "The purpose of this study was to synthesize copolymers of different molecular architecture, i.e., monomer distribution over the polymer chain, and to compare their physical and mechanical properties. A series of random copolymers of 2-ethyl-2-oxazoline (EtOx) and 2-nonyl-2-oxazoline (NonOx) were synthesized via a cationic ring-opening polymerization procedure in acetonitrile under microwave irradiation. The polymerization kinetics for EtOx and NonOx were studied in refluxing butyronitrile using thermal heating. The resulting kinetic data were applied to synthesize a series of block copolymers with the same chemical composition as the random copolymers. The random and block copolymers exhibited the desired composition, molecular weight, and narrow molecular weight distribution. The surface energies of the random copolymers with 65−85 wt % NonOx were higher than the surface energy of their block copolymer counterparts as the random distribution of EtOx units hindered the segregation of the NonOx units to the surface. The variation in polymer architecture also resulted in different phase segregation behavior and different transition temperatures, as shown by differential scanning calorimetry (DSC). The observed elastic moduli, which differed considerably between the random and the block series, were well explained by the phases identified through DSC." @default.
• W2149128236 created "2016-06-24" @default.
• W2149128236 creator A5040157919 @default.
• W2149128236 creator A5046737732 @default.
• W2149128236 creator A5048904641 @default.
• W2149128236 creator A5055866783 @default.
• W2149128236 creator A5061184642 @default.
• W2149128236 creator A5066976932 @default.
• W2149128236 creator A5068648335 @default.
• W2149128236 creator A5069457654 @default.
• W2149128236 creator A5070808413 @default.
• W2149128236 creator A5073464447 @default.
• W2149128236 creator A5081687607 @default.
• W2149128236 creator A5091613350 @default.
• W2149128236 date "2007-07-10" @default.
• W2149128236 modified "2023-10-14" @default.
• W2149128236 title "Synthesis and Structure−Property Relationships of Random and Block Copolymers: A Direct Comparison for Copoly(2-oxazoline)s" @default.
• W2149128236 cites W1537489237 @default.
• W2149128236 cites W1975049557 @default.
• W2149128236 cites W1978627282 @default.
• W2149128236 cites W1991700355 @default.
• W2149128236 cites W2012937953 @default.
• W2149128236 cites W2029670625 @default.
• W2149128236 cites W2033610208 @default.
• W2149128236 cites W2038336213 @default.
• W2149128236 cites W2079556026 @default.
• W2149128236 cites W2086933933 @default.
• W2149128236 cites W2107414539 @default.
• W2149128236 cites W2117203164 @default.
• W2149128236 cites W2126394886 @default.
• W2149128236 cites W2139408955 @default.
• W2149128236 cites W2141888014 @default.
• W2149128236 cites W2143350791 @default.
• W2149128236 cites W2147374860 @default.
• W2149128236 cites W4237567860 @default.
• W2149128236 cites W4247384567 @default.
• W2149128236 doi "https://doi.org/10.1021/ma070720r" @default.
• W2149128236 hasPublicationYear "2007" @default.
• W2149128236 type Work @default.
• W2149128236 sameAs 2149128236 @default.
• W2149128236 citedByCount "71" @default.
• W2149128236 countsByYear W21491282362012 @default.
• W2149128236 countsByYear W21491282362013 @default.
• W2149128236 countsByYear W21491282362014 @default.
• W2149128236 countsByYear W21491282362015 @default.
• W2149128236 countsByYear W21491282362016 @default.
• W2149128236 countsByYear W21491282362017 @default.
• W2149128236 countsByYear W21491282362018 @default.
• W2149128236 countsByYear W21491282362019 @default.
• W2149128236 countsByYear W21491282362020 @default.
• W2149128236 countsByYear W21491282362021 @default.
• W2149128236 countsByYear W21491282362022 @default.
• W2149128236 countsByYear W21491282362023 @default.
• W2149128236 crossrefType "journal-article" @default.
• W2149128236 hasAuthorship W2149128236A5040157919 @default.
• W2149128236 hasAuthorship W2149128236A5046737732 @default.
• W2149128236 hasAuthorship W2149128236A5048904641 @default.
• W2149128236 hasAuthorship W2149128236A5055866783 @default.
• W2149128236 hasAuthorship W2149128236A5061184642 @default.
• W2149128236 hasAuthorship W2149128236A5066976932 @default.
• W2149128236 hasAuthorship W2149128236A5068648335 @default.
• W2149128236 hasAuthorship W2149128236A5069457654 @default.
• W2149128236 hasAuthorship W2149128236A5070808413 @default.
• W2149128236 hasAuthorship W2149128236A5073464447 @default.
• W2149128236 hasAuthorship W2149128236A5081687607 @default.
• W2149128236 hasAuthorship W2149128236A5091613350 @default.
• W2149128236 hasConcept C121332964 @default.
• W2149128236 hasConcept C122865956 @default.
• W2149128236 hasConcept C127413603 @default.
• W2149128236 hasConcept C158117686 @default.
• W2149128236 hasConcept C15920480 @default.
• W2149128236 hasConcept C159985019 @default.
• W2149128236 hasConcept C166940927 @default.
• W2149128236 hasConcept C183882617 @default.
• W2149128236 hasConcept C188027245 @default.
• W2149128236 hasConcept C192562407 @default.
• W2149128236 hasConcept C39519442 @default.
• W2149128236 hasConcept C42360764 @default.
• W2149128236 hasConcept C44228677 @default.
• W2149128236 hasConcept C521977710 @default.
• W2149128236 hasConcept C97355855 @default.
• W2149128236 hasConceptScore W2149128236C121332964 @default.
• W2149128236 hasConceptScore W2149128236C122865956 @default.
• W2149128236 hasConceptScore W2149128236C127413603 @default.
• W2149128236 hasConceptScore W2149128236C158117686 @default.
• W2149128236 hasConceptScore W2149128236C15920480 @default.
• W2149128236 hasConceptScore W2149128236C159985019 @default.
• W2149128236 hasConceptScore W2149128236C166940927 @default.
• W2149128236 hasConceptScore W2149128236C183882617 @default.
• W2149128236 hasConceptScore W2149128236C188027245 @default.
• W2149128236 hasConceptScore W2149128236C192562407 @default.
• W2149128236 hasConceptScore W2149128236C39519442 @default.
• W2149128236 hasConceptScore W2149128236C42360764 @default.
• W2149128236 hasConceptScore W2149128236C44228677 @default.
• W2149128236 hasConceptScore W2149128236C521977710 @default.
• W2149128236 hasConceptScore W2149128236C97355855 @default.
• W2149128236 hasIssue "16" @default.
• W2149128236 hasLocation W21491282361 @default.

• next