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- W2149138512 abstract "Abstract The reactivity of the iminodiphosphane C 6 H 4 ( o ‐CN)N=PPh 2 −PPh 2 , which contains an N=P−P unit, has been investigated. Reaction with small molecules, [viz. H 2 O/O 2 , H 2 O 2 , CH 3 OH, C 6 H 4 ( o ‐CN)NH 2 ] and elemental sulfur result in cleavage of the P−P bond to give aminophosphane‐derivatised compounds. The products from these reactions have been characterized spectroscopically, including two by single‐crystal X‐ray diffraction. The reactivity of the iminodiphosphane towards the transition metal complexes [M(cod)Cl 2 ] (M = Pd or Pt) has also been investigated. In the reactions, the iminodiphosphane rearranges to form the more common diphosphonylamine (P−N−P) unit which chelates to the metal centres. Three different compounds were isolated from these reactions and they have all been fully characterised by spectroscopy and single‐crystal X‐ray diffraction. (© Wiley‐VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2004)" @default.
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- W2149138512 date "2004-01-26" @default.
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- W2149138512 title "On the Reactivity of the Iminodiphosphane C<sub>6</sub>H<sub>4</sub>(<i>o</i>‐CN)N=PPh<sub>2</sub>−PPh<sub>2</sub>: Fragmentation Versus Isomerisation" @default.
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- W2149138512 doi "https://doi.org/10.1002/ejic.200300529" @default.
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