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• W2149153992 abstract "Abstract Shuttling of soluble polysulfide species within electrodes is one of the most challenging issues in lithium–sulfur (Li–S) batteries. The resulting deposition of polysulfide species reduces the conductivity of the metallic Li electrode and the quantity of active material. Here, we demonstrate pronounced suppression of polysulfide shuttle using a sulfide‐impermeable glass‐ceramic membrane, which is employed as separator between the positive and negative electrodes. As a result, highly stable Li–S electrochemistry occurs in the sulfur‐dissolving tetrahydrofuran catholyte solution, which provides good capacity retention and Coulombic efficiency for cycling. This demonstration holds promise for practical next‐generation batteries with marked reversibility and the possibility to increase the energy density when equipped with a catholyte flow‐through mode." @default.
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• W2149153992 date "2015-10-28" @default.
• W2149153992 modified "2023-10-06" @default.
• W2149153992 title "Sulfur-Based Catholyte Solution with a Glass-Ceramic Membrane for Li-S Batteries" @default.
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• W2149153992 doi "https://doi.org/10.1002/celc.201500342" @default.
• W2149153992 hasPublicationYear "2015" @default.
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