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- W2149167368 abstract "The dielectric behaviour of five homologous 4-n-alkyloxy-benzylidene-amino-4′-cyanobiphenyls was investigated. Especially, we were interested in the dielectric relaxation frequencies of the smectic low temperature phases SB and SE as well as the dielectric behaviour in the solid state. We have found in all liquid crystalline phases a low frequency relaxation region explained by a hindered rotation of the molecules around their short axes. By supercooling of the hexyl and heptyl derivatives a new liquid crystalline phase can be obtained. A dielectric relaxation in the solid phase could not be found. Das dielektrische Verhalten von fünf homologen 4-n-Alkyloxybenzylidenamino-4′ cyanobiphenylen wurde untersucht. Wir waren speziell an den dielektrischen Relaxationsfrequenzen in den smektischen Tieftemperaturphasen SB und SB sowie am dielektrischen Verhalten der festen Phase interessiert. In allen flüssigkristallinen Phasen haben wir ein niederfrequentes Relaxationsgebiet gefunden, das durch die gehinderte Rotation der Moleküle um ihre kurzen Achsen erklärt werden kann. Durch Unterkühlen des Hexyl- und Heptylderivates konnte eine neue flüssig-kristalline Phase erhalten werden. Eine dielektrische Relexation in fester Phase konnte nicht gefunden werden." @default.
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- W2149167368 date "1982-01-01" @default.
- W2149167368 modified "2023-09-23" @default.
- W2149167368 title "Dielectric Relaxation in Low Temperature Smectic Phases of 4-n-Alkyloxy-benzylidene-amino-4′-cyanobiphenyls" @default.
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- W2149167368 doi "https://doi.org/10.1002/crat.2170170717" @default.
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