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• W2149167788 abstract "The space group of the trigonal phase of the FeCl, FeBr, FeI, CoCl, and ZnCl boracites is established as C. Ferroelectricity is evidenced by domain switching. High coercive fields at room temperature (up to 800 kV/cm) are found. Polarization-microscopical studies show that the polarization vector is not reversible by 180° but can jump only from, e.g., [111] to [111], [111], or [111], etc., in accord with crystal structure and group theoretical symmetry considerations. Two twinning “laws” are observed: a) head—head (tail—tail) domains with {110}cub as composition plane and b) head—tail domains with {100}cub as composition plane. The domain structure and the relevant twinning operations are discussed. The onset of ferromagnetism at low temperature in FeCl, FeBr, FeI, and CoCl boracites leads to ferromagnetoelectricity. In the case of CoCl boracite the ferromagentoelectric point group is m. Die Raumgruppe der trigonalen Phase der FeCl-, FeBr-, FeI-, CoCl- und ZnCl-Borazite wurde zu C bestimmt. Ferroelektrizität wird durch Bereichumklappung nachgewiesen. Die Koerzitivfelder bei Zimmertemperatur sind sehr hoch (bis zu 800 kV/cm). Polarisationsmikroskopische Studien zeigen, daß der Polarisationsvektor nicht um 180° umklappbar ist, sondern nur von z. B. [111] nach [111], [111], oder [111] usw. springen kann. Dies steht in Übereinstimmung mit der Kristallstruktur und Symmetriebetrachtungen. Zwei Zwillings„gesetze”︁ treten auf: a) Kopf—Kopf (Schwanz—Schwanz) -Bereiche mit {110}cub und b) Kopf—Schwanz-Bereiche mit {100}cub als Verwachsungsebene. Die Bereichstruktur und die entsprechenden Zwillingsoperationen werden besprochen. Das Auftreten von Ferromagnetismus bei tiefen Temperaturen führt bei FeCl-, FeBr-, FeI- und CoCl-Boraziten zu Ferromagnetoelektrizität. CoCl-Borazit hat die ferromagnetoelektrische Punktgruppe m." @default.
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• W2149167788 date "1970-01-01" @default.
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• W2149167788 title "Trigonal Boracites — A New Type of Ferroelectric and Ferromagnetoelectric that Allows no 180° Electric Polarization Reversal" @default.
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• W2149167788 doi "https://doi.org/10.1002/pssb.19700370125" @default.
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