FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W2149170302> ?p ?o ?g. }

• W2149170302 endingPage "7517" @default.
• W2149170302 startingPage "7517" @default.
• W2149170302 abstract "The interaction of sodium octanoate, decanoate or dodecanoate with calcium(II) in aqueous solutions has been studied using turbidity, conductivity and potentiometric measurements. These show a marked alkyl chain length dependence on the behaviour. At the calcium concentration used (1.0 mM), there is little interaction with the octanoate, the decanoate shows initially formation of a 1 ∶ 1 complex, followed by precipitation, while the dodecanoate precipitates at low surfactant concentrations. The solid calcium carboxylates were prepared, and show lamellar, bilayer structures with planes of calcium(II) ions coordinated to carboxylate groups through bidentate chelate linkages. Thermogravimetry and elemental analyses indicate the presence of coordinated water with the calcium decanoate but not with longer chain carboxylates. The results of both the solution and solid state studies suggest that precipitation of long-chain carboxylates depends on a balance between hydration effects and hydrophobic (largely van der Waals') interactions. Electrostatic effects make little energetic contribution but play the important structural role of ordering the carboxylate anions before precipitation. Differences are observed in the interactions between calcium(II) and long chain alkylcarboxylates and alkylsulfates, and are interpreted in terms of stronger binding to the metal of the carboxylate group. A general mechanism is proposed for calcium carboxylate precipitation from aqueous solution based on this and previous studies." @default.
• W2149170302 created "2016-06-24" @default.
• W2149170302 creator A5011321650 @default.
• W2149170302 creator A5038899622 @default.
• W2149170302 creator A5039367332 @default.
• W2149170302 creator A5047738872 @default.
• W2149170302 date "2012-01-01" @default.
• W2149170302 modified "2023-09-27" @default.
• W2149170302 title "What drives the precipitation of long-chain calcium carboxylates (soaps) in aqueous solution?" @default.
• W2149170302 cites W100328325 @default.
• W2149170302 cites W1017991239 @default.
• W2149170302 cites W1541788187 @default.
• W2149170302 cites W1965011740 @default.
• W2149170302 cites W1973309661 @default.
• W2149170302 cites W1974814485 @default.
• W2149170302 cites W1977561482 @default.
• W2149170302 cites W1977854497 @default.
• W2149170302 cites W1979259633 @default.
• W2149170302 cites W1982067898 @default.
• W2149170302 cites W1983292297 @default.
• W2149170302 cites W1983381760 @default.
• W2149170302 cites W1984733628 @default.
• W2149170302 cites W1985076242 @default.
• W2149170302 cites W1985483192 @default.
• W2149170302 cites W1986199753 @default.
• W2149170302 cites W1986991120 @default.
• W2149170302 cites W1992722414 @default.
• W2149170302 cites W1992869137 @default.
• W2149170302 cites W1994695387 @default.
• W2149170302 cites W1996090173 @default.
• W2149170302 cites W1997715985 @default.
• W2149170302 cites W1997988238 @default.
• W2149170302 cites W1998194609 @default.
• W2149170302 cites W1998453383 @default.
• W2149170302 cites W1998594916 @default.
• W2149170302 cites W2000966264 @default.
• W2149170302 cites W2004684812 @default.
• W2149170302 cites W2005294752 @default.
• W2149170302 cites W2008440393 @default.
• W2149170302 cites W2010117392 @default.
• W2149170302 cites W2010295700 @default.
• W2149170302 cites W2010335314 @default.
• W2149170302 cites W2011140625 @default.
• W2149170302 cites W2013196901 @default.
• W2149170302 cites W2013814138 @default.
• W2149170302 cites W2022202003 @default.
• W2149170302 cites W2024087395 @default.
• W2149170302 cites W2025480249 @default.
• W2149170302 cites W2032642369 @default.
• W2149170302 cites W2033516233 @default.
• W2149170302 cites W2036330496 @default.
• W2149170302 cites W2040086195 @default.
• W2149170302 cites W2040635716 @default.
• W2149170302 cites W2042976956 @default.
• W2149170302 cites W2044596960 @default.
• W2149170302 cites W2044631233 @default.
• W2149170302 cites W2046628914 @default.
• W2149170302 cites W2050743142 @default.
• W2149170302 cites W2052978632 @default.
• W2149170302 cites W2053535968 @default.
• W2149170302 cites W2054283198 @default.
• W2149170302 cites W2055942778 @default.
• W2149170302 cites W2056624696 @default.
• W2149170302 cites W2058027358 @default.
• W2149170302 cites W2058702619 @default.
• W2149170302 cites W2064579688 @default.
• W2149170302 cites W2069074944 @default.
• W2149170302 cites W2073202945 @default.
• W2149170302 cites W2081852547 @default.
• W2149170302 cites W2089978198 @default.
• W2149170302 cites W2092833844 @default.
• W2149170302 cites W2107395868 @default.
• W2149170302 cites W2113020738 @default.
• W2149170302 cites W2127401846 @default.
• W2149170302 cites W2137872287 @default.
• W2149170302 cites W2139256274 @default.
• W2149170302 cites W2140800223 @default.
• W2149170302 cites W2162475435 @default.
• W2149170302 cites W2315998413 @default.
• W2149170302 cites W2318268294 @default.
• W2149170302 cites W2324914482 @default.
• W2149170302 cites W2331681865 @default.
• W2149170302 cites W4211103791 @default.
• W2149170302 cites W4237177158 @default.
• W2149170302 doi "https://doi.org/10.1039/c2cp24152h" @default.
• W2149170302 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/22513819" @default.
• W2149170302 hasPublicationYear "2012" @default.
• W2149170302 type Work @default.
• W2149170302 sameAs 2149170302 @default.
• W2149170302 citedByCount "20" @default.
• W2149170302 countsByYear W21491703022012 @default.
• W2149170302 countsByYear W21491703022014 @default.
• W2149170302 countsByYear W21491703022015 @default.
• W2149170302 countsByYear W21491703022016 @default.
• W2149170302 countsByYear W21491703022017 @default.
• W2149170302 countsByYear W21491703022018 @default.
• W2149170302 countsByYear W21491703022019 @default.
• W2149170302 countsByYear W21491703022020 @default.

• next