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- W2149170762 abstract "The syntheses, crystal structures, and NMR and Raman spectroscopic characterization of two compounds with a new member of the organically functionalized dimeric Ge9–Ge9 polyanion [R–Ge9–Ge9–R]4– with R = CH=CH2 are presented. [K([2.2.2]crypt)]4[(CH2=CH)–Ge9–Ge9–(CH=CH2)]·1.76 en (1) was synthesized either at elevated temperature by the reaction of K4Ge9 and bis(trimethylsilyl)acetylene in ethylenediamine or at ambient temperature in the presence of Pt(PPh3)4. [K(18crown-6)]4[(CH2=CH)–Ge9–Ge9–(CH=CH2)]·4 en (2) was obtained from the prefabricated monomeric bisvinylated Ge9 cluster [Ge9(CH=CH2)2]2– and an ethylenediamine solution of the intermetallic compound K4.79Co0.79Sn9. The reductive cleavage of one or two vinyl groups from [Ge9(CH=CH2)2]2– – a prerequisite for the latter reaction – could be shown by reacting a solution of the divinylated [Ge9(CH=CH2)2]2– anion in liquid ammonia with elemental potassium, which resulted in the formation of the ligand-free Ge94– cluster in the new compound [K5(OH)]Ge9(NH3)11 (3)." @default.
- W2149170762 created "2016-06-24" @default.
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- W2149170762 date "2015-04-23" @default.
- W2149170762 modified "2023-09-24" @default.
- W2149170762 title "Bisvinylated [<i>R</i>-Ge<sub>9</sub>-Ge<sub>9</sub>-<i>R</i>]<sup>4-</sup>Cluster Dimers" @default.
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- W2149170762 doi "https://doi.org/10.1002/zaac.201500131" @default.
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