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- W2149182110 abstract "Abstract The P−T phase diagram associated with the ferromagnetic semiconductor CdCr2Se4 was determined between 600 and 964°C for the first time from the PSe2(or Cd) − T diagram for the stability of the compound disclosed by annealing experiments under controlled Se2 and Cd vapor pressures, and from the phase equilibria in the CdSeCrSeSe system examined by usual annealing experiments. The following characteristic features are also clarified. (1) The maximum temperature for the stability of CdCr2Se4 is about 900°C. (2) CdCr2Se4 dissolves into Se melt and is in equilibrium with the Se-rich melt which has a CdSe content in excess of CdSe·Cr2Se3. The solubility decreases rapidly as temperature falls from 900 to 860°C. (3) Cr2Se3 is the only compound in the CrSe system in equilibrium with CdCr2Se4 above about 860°C. Both Cr3Se4 and Cr2Se3 exist below this temperature. (4) The PSe2 range for the stability of CdCr2Se4 is estimated as a measure of the concentration ranges of native defects due to nonstoichiometry. It increases as temperature decreases and is about 5 × 109 at 600°C." @default.
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- W2149182110 date "1977-01-01" @default.
- W2149182110 modified "2023-09-24" @default.
- W2149182110 title "P−T phase diagram for ferromagnetic semiconductor CdCr2Se4†" @default.
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- W2149182110 doi "https://doi.org/10.1016/0022-3697(77)90227-x" @default.
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