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- W2149193713 abstract "The emissions of the 0–0 and 1–1 bands of the O 2 (b 1 ∑ g + →X 3 ∑ g − transition have been observed at 762 and 771 nm respectively in the photolysis of O 3 /O 2 /Ar mixtures at 253.7 nm. From the dependence of these emissions on the concentration of oxygen for various ozone concentrations the following conclusions can be drawn: one-quarter to one-half of the O 2 (b 1 ∑ g + ) molecules formed in the energy transfer from O(2 1 D 2 ) to O 2 (X 3 ∑ g − ) are in the vibrational state &([a-z]+);′ = 1, the remainder being in the &([a-z]+);′ = 0 state. Furthermore, it is shown that O 3 deactivates O(2 1 D 2 ) eight times more effectively than O 2 . The relative rates of the reactions of O 2 (b 1 ∑ g + ), &([a-z]+);′ = 1 with O 2 and O 3 are also discussed and approximate values of 0.6 and 1.0 are determined relative to the rate of the reaction of O 2 (b 1 ∑ g + ), &([a-z]+);′ = 0 with O 3 ." @default.
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- W2149193713 date "1974-12-15" @default.
- W2149193713 modified "2023-10-14" @default.
- W2149193713 title "Production de O<sub>2</sub>(<i>b</i><sup>1</sup>∑<sub>g</sub><sup>+</sup>), &([a-z]+);′ = 0, 1 et 2 par la reaction O(2<sup>1</sup>D<sub>2</sub>) + O<sub>2</sub>(<i>X</i><sup>3</sup>∑<sub>g</sub><sup>−</sup>)" @default.
- W2149193713 doi "https://doi.org/10.1139/v74-598" @default.
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