FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W2149222794> ?p ?o ?g. }

• W2149222794 endingPage "2398" @default.
• W2149222794 startingPage "2392" @default.
• W2149222794 abstract "Turning molecular recognition into an effective mechanical response is critical for many applications ranging from molecular motors and responsive materials to sensors. Herein, we demonstrate how the energy of the molecular recognition between a supramolecular host and small alkylammonium salts can be harnessed to perform a nanomechanical task in a univocal way. Nanomechanical Si microcantilevers (MCs) functionalized by a film of tetra-phosphonate cavitands were employed to screen as guests the compounds of the butylammonium chloride series 1–4, which comprises a range of low molecular weight (LMW) molecules (molecular mass < 150 Da) that differ from each other by one or a few N-methyl groups (molecular mass 15 Da). The cavitand surface recognition of each individual guest drove a specific MC bending (from a few to several tens of nanometer), disclosing a direct, label-free, and real-time mean to sort them. The complexation preferences of tetraphosphonate cavitands toward ammonium chloride guests 1–4 were independently assessed by isothermal titration calorimetry. Both direct and displacement binding experiments concurred to define the following binding order in the alkylammonium series: 2 > 3 ≈ 1 ≫ 4. This trend is consistent with the number of interactions established by each guest with the host. The complementary ITC experiments showed that the host–guest complexation affinity in solution is transferred to the MC bending. These findings were benchmarked by implementing cavitand-functionalized MCs to discriminate sarcosine from glycine in water." @default.
• W2149222794 created "2016-06-24" @default.
• W2149222794 creator A5000990562 @default.
• W2149222794 creator A5022146909 @default.
• W2149222794 creator A5032922582 @default.
• W2149222794 creator A5048844125 @default.
• W2149222794 creator A5049681508 @default.
• W2149222794 creator A5053161524 @default.
• W2149222794 creator A5062931738 @default.
• W2149222794 creator A5067802256 @default.
• W2149222794 date "2012-01-24" @default.
• W2149222794 modified "2023-09-25" @default.
• W2149222794 title "Nanomechanical Recognition of <i>N</i>-Methylammonium Salts" @default.
• W2149222794 cites W1973169290 @default.
• W2149222794 cites W1974383036 @default.
• W2149222794 cites W1974588832 @default.
• W2149222794 cites W1979426979 @default.
• W2149222794 cites W1981556737 @default.
• W2149222794 cites W1984740654 @default.
• W2149222794 cites W1986048323 @default.
• W2149222794 cites W2002192602 @default.
• W2149222794 cites W2002920612 @default.
• W2149222794 cites W2016087445 @default.
• W2149222794 cites W2016710911 @default.
• W2149222794 cites W2036964573 @default.
• W2149222794 cites W2041541639 @default.
• W2149222794 cites W2062866182 @default.
• W2149222794 cites W2063244563 @default.
• W2149222794 cites W2077777805 @default.
• W2149222794 cites W2084837673 @default.
• W2149222794 cites W2090550873 @default.
• W2149222794 cites W2101884223 @default.
• W2149222794 cites W2122310210 @default.
• W2149222794 cites W2124585400 @default.
• W2149222794 cites W2126985423 @default.
• W2149222794 cites W2127601551 @default.
• W2149222794 cites W2130002767 @default.
• W2149222794 cites W2141136288 @default.
• W2149222794 cites W2155680682 @default.
• W2149222794 cites W2163953306 @default.
• W2149222794 cites W2479588146 @default.
• W2149222794 cites W2950631786 @default.
• W2149222794 cites W2950883063 @default.
• W2149222794 cites W4248094395 @default.
• W2149222794 cites W4250122831 @default.
• W2149222794 cites W4253361987 @default.
• W2149222794 cites W4376849539 @default.
• W2149222794 doi "https://doi.org/10.1021/ja210567k" @default.
• W2149222794 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/22239344" @default.
• W2149222794 hasPublicationYear "2012" @default.
• W2149222794 type Work @default.
• W2149222794 sameAs 2149222794 @default.
• W2149222794 citedByCount "35" @default.
• W2149222794 countsByYear W21492227942012 @default.
• W2149222794 countsByYear W21492227942013 @default.
• W2149222794 countsByYear W21492227942014 @default.
• W2149222794 countsByYear W21492227942015 @default.
• W2149222794 countsByYear W21492227942016 @default.
• W2149222794 countsByYear W21492227942017 @default.
• W2149222794 countsByYear W21492227942018 @default.
• W2149222794 countsByYear W21492227942019 @default.
• W2149222794 countsByYear W21492227942020 @default.
• W2149222794 crossrefType "journal-article" @default.
• W2149222794 hasAuthorship W2149222794A5000990562 @default.
• W2149222794 hasAuthorship W2149222794A5022146909 @default.
• W2149222794 hasAuthorship W2149222794A5032922582 @default.
• W2149222794 hasAuthorship W2149222794A5048844125 @default.
• W2149222794 hasAuthorship W2149222794A5049681508 @default.
• W2149222794 hasAuthorship W2149222794A5053161524 @default.
• W2149222794 hasAuthorship W2149222794A5062931738 @default.
• W2149222794 hasAuthorship W2149222794A5067802256 @default.
• W2149222794 hasConcept C147597530 @default.
• W2149222794 hasConcept C147789679 @default.
• W2149222794 hasConcept C156911925 @default.
• W2149222794 hasConcept C178790620 @default.
• W2149222794 hasConcept C179303850 @default.
• W2149222794 hasConcept C184866935 @default.
• W2149222794 hasConcept C185592680 @default.
• W2149222794 hasConcept C21951064 @default.
• W2149222794 hasConcept C2777454769 @default.
• W2149222794 hasConcept C2777626080 @default.
• W2149222794 hasConcept C2777735830 @default.
• W2149222794 hasConcept C29152607 @default.
• W2149222794 hasConcept C32909587 @default.
• W2149222794 hasConcept C59593255 @default.
• W2149222794 hasConcept C69169829 @default.
• W2149222794 hasConcept C8010536 @default.
• W2149222794 hasConcept C93275456 @default.
• W2149222794 hasConceptScore W2149222794C147597530 @default.
• W2149222794 hasConceptScore W2149222794C147789679 @default.
• W2149222794 hasConceptScore W2149222794C156911925 @default.
• W2149222794 hasConceptScore W2149222794C178790620 @default.
• W2149222794 hasConceptScore W2149222794C179303850 @default.
• W2149222794 hasConceptScore W2149222794C184866935 @default.
• W2149222794 hasConceptScore W2149222794C185592680 @default.
• W2149222794 hasConceptScore W2149222794C21951064 @default.
• W2149222794 hasConceptScore W2149222794C2777454769 @default.
• W2149222794 hasConceptScore W2149222794C2777626080 @default.

• next