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- W2149254001 abstract "Abstract Normal coordinate analysis (NCA) of some disilene and diphosphene molecules has been performed and compared with NCA of corresponding alkenes. For various models of disilenes containing the C 2 SiSiC 2 moiety, NCA shows that SiSi and SiC stretching coordinates are heavily mixed, their in-phase combination resulting in a normal mode in the region 450–550 cm −1 , while their out-of-phase combination is in the region 600–750 cm −1 . In contrast, the results of NCA for diphosphenes show that the vibration at ≈ 600 cm −1 is well localized, being predominantly νPP stretch (≈ 90% in PED)." @default.
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- W2149254001 date "1997-06-01" @default.
- W2149254001 modified "2023-10-18" @default.
- W2149254001 title "Normal coordinate analysis of disilenes and diphosphenes. The ν(SiSi) and ν(PP) stretching vibrations" @default.
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- W2149254001 doi "https://doi.org/10.1016/s0022-2860(96)09508-7" @default.
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