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• W2149281625 abstract "New transient arenesulfenic acids were involved in the synthesis of enantiopure 2-arylsulfinyl-1,3-dienes, showing central or axial chirality of the substituted arene residue, apart from the chirality related to the stereogenic sulfur atom. Some of the obtained dienes, that is, (Sa,SS)- and (SaRS)-2-(2′-hydroxy-1,1′-binaphthalen-2-sulfinyl)-3-methyl-1,3-butadienes, were subjected to diastereoselective Diels–Alder cycloadditions with N-methylmaleimide. Removal of the arylsulfoxide auxiliary, in the major adduct, was accomplished by reductive cleavage with Raney nickel." @default.
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• W2149281625 date "2005-12-01" @default.
• W2149281625 modified "2023-09-27" @default.
• W2149281625 title "Enantiopure arenesulfenic acids as intermediates in stereoselective synthesis" @default.
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• W2149281625 doi "https://doi.org/10.1016/j.tet.2005.09.052" @default.
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