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- W2149301817 abstract "Described herein is the development of the B(C6F5)3-catalyzed hydrosilylation of α,β-unsaturated esters and amides to afford synthetically valuable α-silyl carbonyl products. The α-silylation occurs chemoselectively, thus leaving the labile carbonyl groups intact. The reaction features a broad scope of both acyclic and cyclic substrates, and the synthetic utility of the obtained α-silyl carbonyl products is also demonstrated. Mechanistic studies revealed two operative steps: fast 1,4-hydrosilylation of conjugated carbonyls and then slow silyl group migration of a silyl ether intermediate." @default.
- W2149301817 created "2016-06-24" @default.
- W2149301817 creator A5043137954 @default.
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- W2149301817 date "2015-11-09" @default.
- W2149301817 modified "2023-10-17" @default.
- W2149301817 title "Borane-Catalyzed Reductive α-Silylation of Conjugated Esters and Amides Leaving Carbonyl Groups Intact" @default.
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- W2149301817 doi "https://doi.org/10.1002/anie.201508669" @default.
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