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- W2149305708 abstract "Abstract Kinetic study of the α‐lithiation of benzyl methyl ether (BME) by n BuLi has revealed that increasing the concentration of the organolithium compound does not necessarily increase the reactivity, and this is a consequence of the reactivities of the different n BuLi aggregates present in solution. We propose a dimer‐based mechanism, in which a pre‐complexation step is a key process for substrates bearing a donor oxygen atom that can interact with the lithium cation to form mixed dimers. For these studies, we have developed a system based on UV/Vis spectroscopy that allows kinetic measurements to be conducted at −80 °C under argon." @default.
- W2149305708 created "2016-06-24" @default.
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- W2149305708 date "2013-06-05" @default.
- W2149305708 modified "2023-10-18" @default.
- W2149305708 title "Mechanism of the Deprotonation Reaction of Alkyl Benzyl Ethers with<i>n</i>-Butyllithium" @default.
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- W2149305708 doi "https://doi.org/10.1002/chem.201204467" @default.
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