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• W2149308832 abstract "The first kinetically stabilized azete, the title compound 1, is sensitive toward oxidation (→ formation of the dioxetane 2) and undergoes hydrolysis to the β-imino ketone 3. Sterically nondemanding cycloaddition partners such as cyclopentadiene or diazomethane (CH2N2) (→ formation of the adduct 4) attack at C-2/C-3, whereas those with bulky groups such as acetylenedicarboxylate esters or tert-butylphosphaacetylene (PCtBu) (→ formation of the bicyclic compound 5) react at N-1/C-4." @default.
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• W2149308832 date "1988-02-01" @default.
• W2149308832 modified "2023-09-27" @default.
• W2149308832 title "Reactivity of Tri-tert-butylazete" @default.
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• W2149308832 doi "https://doi.org/10.1002/anie.198802721" @default.
• W2149308832 hasPublicationYear "1988" @default.
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