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- W2149336346 abstract "Abstract A heterogeneous palladium catalyst supported on a ceramic (5 % Pd/ceramic) was developed. The catalyst exhibited a specific chemoselectivity for hydrogenation that has never been achieved by other palladium‐catalyzed methods. Either aliphatic or aromatic N ‐Cbz groups could be deprotected to the corresponding free‐amines, while the hydrogenolysis of benzyl esters and ethers did not proceed. Furthermore, aryl chlorides and epoxides were tolerant under the Pd/ceramic‐catalyzed hydrogenation conditions. 5 % Pd/ceramic could be reused without any loss of catalyst activity, as no palladium leaching was detected in the reaction media." @default.
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- W2149336346 date "2015-05-28" @default.
- W2149336346 modified "2023-10-14" @default.
- W2149336346 title "Unique Chemoselective Hydrogenation using a Palladium Catalyst Immobilized on Ceramic" @default.
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- W2149336346 doi "https://doi.org/10.1002/cctc.201500193" @default.
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