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- W2149366348 abstract "The syntheses, structures and ligand conformations of three Cd(II) coordination polymers [Cd(L1)(ClO4)2]∞ [L1 = N,N′-di(2-pyridyl)adipoamide], 1, {[Cd(L2)2(CH3OH)2](ClO4)2·2CH3OH}∞ [L2 = N,N′-di(3-pyridyl)adipoamide], 2 and [Cd(L3)2(ClO4)2(CH3CH2OH)2]∞ [L3 = N,N′-di(4-pyridyl)adipoamide], 3, are reported. Their structures have been characterized by X-ray crystallography. Complex 1 forms 1D zigzag chains, while complex 2 forms 2D pleated sheets which are positioned in an ABAB manner. Complex 3 shows a rare 3D entanglement from parallel polycatenation of 3-fold interpenetrated square layers. While the L1 ligands in 1 adopt AAAtrans conformations and the L2 ligands in 2 adopt GAGtrans conformations, the L3 ligands in 3 adopt AAAtrans and AGAtrans conformations. The structural types of the Cd(II) coordination polymers can be directed by ligand isomerism." @default.
- W2149366348 created "2016-06-24" @default.
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- W2149366348 date "2009-01-01" @default.
- W2149366348 modified "2023-10-06" @default.
- W2149366348 title "Ligand isomerism-controlled structural diversity of cadmium(II) perchlorate coordination polymers containing dipyridyladipoamide ligands" @default.
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- W2149366348 doi "https://doi.org/10.1039/b812447g" @default.
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