Matches in SemOpenAlex for { <https://semopenalex.org/work/W2149368259> ?p ?o ?g. }
- W2149368259 endingPage "584" @default.
- W2149368259 startingPage "577" @default.
- W2149368259 abstract "It has been recognized previously that inside nanosized cavities like in mesoporous materials a small ensemble situation can be realized. The limited number of reactants per confinement leads to unusual chemical behaviour whenever inter- vs. intramolecular pathways compete against each other. Therefore, the metathesis reaction might represent a chemical process for which the product distribution is influenced by a confining reaction field. In the current paper we report about the unusual reactivity of the Grubbs generation I catalyst inside mesoporous silica materials. It has been observed that due to a combination of confinement and surface effects the Grubbs catalyst is not stable inside small pores. It quickly rearranges to a variety of unexpected products. However, the undesired deactivation of the catalyst can be prohibited by surface modification of the silica surfaces." @default.
- W2149368259 created "2016-06-24" @default.
- W2149368259 creator A5023573203 @default.
- W2149368259 creator A5054631702 @default.
- W2149368259 creator A5055291292 @default.
- W2149368259 date "2010-01-01" @default.
- W2149368259 modified "2023-09-27" @default.
- W2149368259 title "Metathesiscatalysts in confining reaction fields—confinement effects vs. surface effects" @default.
- W2149368259 cites W1487572942 @default.
- W2149368259 cites W1963503284 @default.
- W2149368259 cites W1963611839 @default.
- W2149368259 cites W1965323549 @default.
- W2149368259 cites W1982784029 @default.
- W2149368259 cites W1987048312 @default.
- W2149368259 cites W1995647974 @default.
- W2149368259 cites W1999748098 @default.
- W2149368259 cites W2000343675 @default.
- W2149368259 cites W2003632281 @default.
- W2149368259 cites W2003988833 @default.
- W2149368259 cites W2007524382 @default.
- W2149368259 cites W2012444916 @default.
- W2149368259 cites W2015066782 @default.
- W2149368259 cites W2017917641 @default.
- W2149368259 cites W2025059325 @default.
- W2149368259 cites W2033714240 @default.
- W2149368259 cites W2043135854 @default.
- W2149368259 cites W2043302344 @default.
- W2149368259 cites W2049748813 @default.
- W2149368259 cites W2051976424 @default.
- W2149368259 cites W2060757347 @default.
- W2149368259 cites W2060825261 @default.
- W2149368259 cites W2061055052 @default.
- W2149368259 cites W2063454667 @default.
- W2149368259 cites W2066806118 @default.
- W2149368259 cites W2076672323 @default.
- W2149368259 cites W2090717492 @default.
- W2149368259 cites W2091943316 @default.
- W2149368259 cites W2092984159 @default.
- W2149368259 cites W2104136524 @default.
- W2149368259 cites W2105925720 @default.
- W2149368259 cites W2110180368 @default.
- W2149368259 cites W2112272805 @default.
- W2149368259 cites W2116741024 @default.
- W2149368259 cites W2131537503 @default.
- W2149368259 cites W2151885161 @default.
- W2149368259 cites W2170736857 @default.
- W2149368259 cites W2949536368 @default.
- W2149368259 cites W2952293795 @default.
- W2149368259 cites W4253194572 @default.
- W2149368259 cites W4254594717 @default.
- W2149368259 doi "https://doi.org/10.1039/b911795b" @default.
- W2149368259 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/20023996" @default.
- W2149368259 hasPublicationYear "2010" @default.
- W2149368259 type Work @default.
- W2149368259 sameAs 2149368259 @default.
- W2149368259 citedByCount "14" @default.
- W2149368259 countsByYear W21493682592012 @default.
- W2149368259 countsByYear W21493682592013 @default.
- W2149368259 countsByYear W21493682592014 @default.
- W2149368259 countsByYear W21493682592016 @default.
- W2149368259 countsByYear W21493682592020 @default.
- W2149368259 countsByYear W21493682592021 @default.
- W2149368259 crossrefType "journal-article" @default.
- W2149368259 hasAuthorship W2149368259A5023573203 @default.
- W2149368259 hasAuthorship W2149368259A5054631702 @default.
- W2149368259 hasAuthorship W2149368259A5055291292 @default.
- W2149368259 hasConcept C115537861 @default.
- W2149368259 hasConcept C127413603 @default.
- W2149368259 hasConcept C142724271 @default.
- W2149368259 hasConcept C153914509 @default.
- W2149368259 hasConcept C159467904 @default.
- W2149368259 hasConcept C159985019 @default.
- W2149368259 hasConcept C161790260 @default.
- W2149368259 hasConcept C171250308 @default.
- W2149368259 hasConcept C177801218 @default.
- W2149368259 hasConcept C178790620 @default.
- W2149368259 hasConcept C185592680 @default.
- W2149368259 hasConcept C192562407 @default.
- W2149368259 hasConcept C204787440 @default.
- W2149368259 hasConcept C2776910235 @default.
- W2149368259 hasConcept C2777496208 @default.
- W2149368259 hasConcept C42360764 @default.
- W2149368259 hasConcept C44138296 @default.
- W2149368259 hasConcept C44228677 @default.
- W2149368259 hasConcept C521977710 @default.
- W2149368259 hasConcept C71924100 @default.
- W2149368259 hasConcept C75079739 @default.
- W2149368259 hasConcept C82776694 @default.
- W2149368259 hasConceptScore W2149368259C115537861 @default.
- W2149368259 hasConceptScore W2149368259C127413603 @default.
- W2149368259 hasConceptScore W2149368259C142724271 @default.
- W2149368259 hasConceptScore W2149368259C153914509 @default.
- W2149368259 hasConceptScore W2149368259C159467904 @default.
- W2149368259 hasConceptScore W2149368259C159985019 @default.
- W2149368259 hasConceptScore W2149368259C161790260 @default.
- W2149368259 hasConceptScore W2149368259C171250308 @default.
- W2149368259 hasConceptScore W2149368259C177801218 @default.
- W2149368259 hasConceptScore W2149368259C178790620 @default.