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- W2149447651 abstract "The palladium-catalyzed direct arylation of furan, thiophene, pyrrole, or pyrazole derivatives bearing CONHR substituents on C2, C3, or C5 with aryl bromides was studied. The use of KOAc as the base, DMAc as the solvent, and PdCl(C3H5)(dppb) as the catalyst was found to give regioselectively and without decarbamoylation the arylated heteroaromatics. Under these conditions, the amide substituent on the heteroaromatic does not act as a directing group. A wide range of functional groups such as acetyl, formyl, ester, nitrile, trifluoromethyl, and fluoro on the aryl bromide is tolerated." @default.
- W2149447651 created "2016-06-24" @default.
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- W2149447651 date "2011-06-15" @default.
- W2149447651 modified "2023-09-29" @default.
- W2149447651 title "Palladium-Catalyzed Direct Arylations of Five-Membered Heteroarenes Bearing N-Monoalkylcarboxamide Substituents" @default.
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- W2149447651 doi "https://doi.org/10.1002/ejoc.201100312" @default.
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