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- W2149473007 abstract "Recent reports have highlighted the biological activity associated with a subfamily of the tetramic acid class of natural products. Despite the fact that members of this subfamily act as protein–protein interaction inhibitors that are of relevance to proteasome assembly, no synthetic work has been reported. This may be due to the fact that this subfamily contains an unnatural 4,4-disubstitued glutamic acid, the synthesis of which provides a key challenge. A highly stereoselective route to a masked form of this unnatural amino acid now enabled the synthesis of two of the possible diastereomers of JBIR-22 and allowed the assignment of its relative and absolute stereochemistry." @default.
- W2149473007 created "2016-06-24" @default.
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- W2149473007 date "2015-02-04" @default.
- W2149473007 modified "2023-10-11" @default.
- W2149473007 title "Stereochemical Assignment of the Protein-Protein Interaction Inhibitor JBIR-22 by Total Synthesis" @default.
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- W2149473007 doi "https://doi.org/10.1002/anie.201411141" @default.
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