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- W2149476477 abstract "Single-crystal X-ray diffraction studies illustrate that the three title compounds are isomorphous, belonging to the triclinic space group P[Formula: see text], with slightly distorted trigonal bipyramidal geometry about cobalt. The solid-state 29 Si, 119 Sn, and 207 Pb cross-polarization magic angle spinning (CP MAS) NMR spectra are presented. The indirect spinspin coupling constant (J), quadrupolardipolar shift (d), direct dipolar coupling constant (D' ), anisotropy in spinspin coupling (ΔJ), and the chemical shift tensor were extracted. A plot of the reduced coupling constant vs. s-electron densities at the nucleus indicates that the Fermi contact term may be dominant for the tin and lead complexes; however, the large ΔJ for all complexes indicate that there are also significant anisotropic terms. Trends in the Raman scattering spectra are also discussed.Key words: 29 Si, 119 Sn, and 207 Pb CP MAS NMR, tetracarbonyl cobalt, spinspin coupling, chemical shift tensor, quadrupole coupling, Fermi contact, cobaltgroup 14." @default.
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- W2149476477 date "2002-07-01" @default.
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- W2149476477 title "X-ray diffraction, Raman spectroscopic, and solid-state NMR studies of the group 14 metal-(tetracarbonyl)cobalt complexes Ph<sub>3</sub>MCo(CO)<sub>4</sub> (M = Si, Sn, Pb)" @default.
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- W2149476477 doi "https://doi.org/10.1139/v02-110" @default.
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