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- W2149479160 abstract "Triaryl phosphite complexes of palladium(II) and platinum(II), MX2[P(OAr)3]2(M = Pd or Pt; X = Cl, Br, or I; Ar = phenyl, p-chlorophenyl, o-, m-, or p-tolyl), react in boiling decalin, with elimination of a molecule of hydrogen halide. HX, to afford ortho-metallated triaryl phosphite derivatives. The tendency to undergo metallation is dependent upon the anionic ligands present and increases I < Br < Cl. The structures and stereochemistry of these products have been determined by i.r. and n.m.r. spectroscopy. Treatment of the ortho-metallated complexes with hydrogen halide in dichloromethane leads to rapid reversal of the ortho-palladation reactions and slow reversal of the ortho-platination reactions. Mechanistic aspects of the ortho-metallation processes are discussed." @default.
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- W2149479160 date "1973-01-01" @default.
- W2149479160 modified "2023-09-29" @default.
- W2149479160 title "Transition-metal complexes containing phosphorus ligands. Part X. ortho-Metallation reactions involving some triaryl phosphite derivatives of palladium(II) and platinum(II) dihalides" @default.
- W2149479160 doi "https://doi.org/10.1039/dt9730001151" @default.
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