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- W2149479613 abstract "We report new developments on the chemical vapor deposition growth of 0.4 nm single-walled carbon nanotubes (SWCNTs) inside the linear channels of the aluminophosphate zeolite, AlPO4-5 (AFI), single crystals (0.4 [email protected]). Ethylene (C2H4) and carbon monoxide (CO) were used as the feedstock. Polarized Raman spectroscopy was used to analyze the structure and quality of SWCNTs, both the radial breathing mode and G-band are much clearer and stronger than the samples grown by the old process which used template tripropylamine molecules for growing [email protected] From the Raman spectra, it is clearly seen that the RBM is composed of two peaks at 535 and 551 cm−1. By using the pseudopotential module in Material Studio to calculate the Raman lines, the 535 cm−1 peak is attributed to the (5,0) SWCNTs and the 551 cm−1 peak to the (3,3) SWCNTs. The abundance of (4,2) is relatively small. Thermal gravity analysis showed that while the samples grown by CO display less than 1 wt% of carbon, for the samples heated in C2H4 atmosphere the weight percentage of SWCNTs is around 10%, which implies ∼30% of the AFI channels are occupied with SWCNTs, a significant increase compared with the previous samples." @default.
- W2149479613 created "2016-06-24" @default.
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- W2149479613 date "2014-09-01" @default.
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- W2149479613 title "New developments in the growth of 4 Angstrom carbon nanotubes in linear channels of zeolite template" @default.
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- W2149479613 doi "https://doi.org/10.1016/j.carbon.2014.04.094" @default.
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