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- W2149489810 abstract "Interfacial phenomena involved in the underpotential deposition of tellurium layers were studied with an electrochemical quartz crystal nanobalance (EQCN) in perchloric acid solution (pH = 1). The in situ study of the oxidation kinetics showed that the oxidation of the Te layer deposited neighbor a Teads/Au provides evidence of TeO2ads formation with the incorporation of oxygen to induce the formation of H2TeO3. From the calculations of the first tellurium layer (82 ng cm−2), the mass expected for the second layer deposited in underpotential control was found. Moreover, the oxidation of Teads followed a bi-functional mechanism involving the oxygen incorporated before the tellurium oxidation at high overpotentials. The combination of powerful interfacial methods (cyclic voltammetry and EQCN) gives a new perspective on tellurium electrodeposition and leads to a comprehensive understanding of the interfacial architecture." @default.
- W2149489810 created "2016-06-24" @default.
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- W2149489810 date "2011-12-01" @default.
- W2149489810 modified "2023-10-16" @default.
- W2149489810 title "Tellurium underpotential deposited ad-atoms on Au electrodes: A new electrodeposition mechanism using an electrochemical quartz crystal nanobalance" @default.
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- W2149489810 doi "https://doi.org/10.1016/j.electacta.2011.07.098" @default.
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