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- W2149498344 abstract "Abstract Mossbauer experiments have been performed in the magnetically ordered phase of RbFeCl3·2H2O and CsFeCl3·2H2O. Magnetic ordering is observed in both compounds, which are reported to show low-dimensional interactions. The observed temperature dependence of the hyperfine field of RbFeCl3·2H2O fits well to the S′ = 1 2 rectangular Ising model, with exchange constants |J1/k| = 50±7 K and |J2/k| = 0.40±0.25 K, and TN = 12.08±0.06 K. The low-temperature orientation of the hyperfine field of RbFeCl3·2H2O has been determined by measurements on a single-crystal absorber in an applied field. The hyperfine field is oriented parallel to the a axis, which deviates slightly from the earlier reported magnetic moment direction at 16° to the a axis. This deviation is attributed to the dipolar contribution in the hyperfine field. The low value of the saturation hyperfine field (-7.5T for RbFeCl3·2H2O) and the relative importance of the dipolar contribution are discussed in relation to the crystal field effects of a tetragonally distorted octahedron." @default.
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- W2149498344 date "1981-11-01" @default.
- W2149498344 modified "2023-09-26" @default.
- W2149498344 title "Magnetic ordering in the compounds RbFeCl3·2H2O and CsFeCl3·2H2O" @default.
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- W2149498344 doi "https://doi.org/10.1016/0378-4363(81)90098-x" @default.
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