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- W2149524273 abstract "Abstract The enantioselective conjugated addition of tritylthiol to in situ generated ortho ‐quinone methides ( o ‐QMs) is catalyzed by an acid–base bifunctional squaramide organocatalyst. The transformation proceeds with high yield (up to 99 %) and stereoselectivity (up to 97:3 e.r.) using water as solvent under mild conditions. The catalyst system provides a new strategy for the synthesis of optically active benzyl mercaptans. Control experiments suggested that o ‐QMs are generated by the tertiary amine moiety of the squaramide organocatalyst and that the water–oil biphase is crucial for achieving high reactivity and stereoselectivity." @default.
- W2149524273 created "2016-06-24" @default.
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- W2149524273 date "2015-02-18" @default.
- W2149524273 modified "2023-10-18" @default.
- W2149524273 title "Formal Asymmetric Catalytic Thiolation with a Bifunctional Catalyst at a Water-Oil Interface: Synthesis of Benzyl Thiols" @default.
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- W2149524273 doi "https://doi.org/10.1002/anie.201409894" @default.
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