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• W2149551449 abstract "Not a catalyst killer: In the reaction of 2 with B(C6F5)3, a nucleophilic aromatic substitution with CF bond cleavage leads to the unexpected difluoride 1. Although the formation of ZrF species during olefin polymerization by [Cp′2ZrR]+[RB(C6F5)3]− (Cp′=substituted or unsubstituted η5-cyclopentadienyl; R=Me, H) catalysts is often described as a deactivation, the catalyst precursor 2 can be regenerated from 1 through treatment with iBu2AlH. Supporting information for this article is available on the WWW under http://www.wiley-vch.de/contents/jc_2002/2006/z600361_s.pdf or from the author. Please note: The publisher is not responsible for the content or functionality of any supporting information supplied by the authors. Any queries (other than missing content) should be directed to the corresponding author for the article." @default.
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• W2149551449 date "2006-06-08" @default.
• W2149551449 modified "2023-10-17" @default.
• W2149551449 title "Formation of Zirconocene Fluoro Complexes: No Deactivation in the Polymerization of Olefins by the Contact-Ion-Pair Catalysts [Cp′2ZrR]+[RB(C6F5)3]−" @default.
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• W2149551449 doi "https://doi.org/10.1002/anie.200600361" @default.
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