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• W2149608722 abstract "The taming of the screw: The CoI-catalyzed cyclotrimerization of triynes and microwave (MW) assisted aromatization with MnO2 are central to the practical synthesis of diaza[5]helicene and aza[6]helicenes. The aza[6]helicene racemates have been resolved, the absolute configuration of the enantiomers assigned, the energy barriers to racemization determined, and X-ray structures of their Ag complexes obtained (see picture; Cp=C5H5, OTf=triflate)." @default.
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• W2149608722 date "2008-04-08" @default.
• W2149608722 modified "2023-10-18" @default.
• W2149608722 title "A Straightforward Route to Helically Chiral N-Heteroaromatic Compounds: Practical Synthesis of Racemic 1,14-Diaza[5]helicene and Optically Pure 1- and 2-Aza[6]helicenes" @default.
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• W2149608722 doi "https://doi.org/10.1002/anie.200705463" @default.
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