Matches in SemOpenAlex for { <https://semopenalex.org/work/W2149642984> ?p ?o ?g. }
- W2149642984 endingPage "241" @default.
- W2149642984 startingPage "233" @default.
- W2149642984 abstract "Two ruthenium(II) carbonyl complexes of porphycene, (carbonyl)(pyridine)(2,7,12,17-tetra-n-propylporphycenato)ruthenium(II) (1) and (carbonyl)(pyridine)(2,3,6,7,12,13,16,17-octaethylpor-phycenato)ruthenium(II) (2), have been structurally characterized by single-crystal X-ray diffraction analysis. Cyclic voltammetry has revealed that the porphycene complexes undergo multiple oxidations and reductions in dichloromethane and the reduction potentials are highly positive compared to porphyrin analogs. UV-light irradiation (400 nm or shorter wavelength region) of a benzene solution of 1 and 2 containing external pyridine leads to dissociation of the carbonyl ligand from the ruthenium(II) centers to give the corresponding bis-pyridine complexes. The identical reaction has been also studied for a porphyrin derivative (carbonyl)(pyridine)(2,3,7,8,12,13,17,18-octaethylporphyriato)ruthenum(II) (3). The first-order kinetic analysis has revealed that the photosubstitution of all of the compounds occurs in the order of 10 -3 s -1 at 298 K but proceeds faster for complexes of porphycene (1 and 2) than that of porphyrin (3)." @default.
- W2149642984 created "2016-06-24" @default.
- W2149642984 creator A5048013176 @default.
- W2149642984 creator A5052621291 @default.
- W2149642984 creator A5054986463 @default.
- W2149642984 creator A5058044716 @default.
- W2149642984 date "2015-01-01" @default.
- W2149642984 modified "2023-10-14" @default.
- W2149642984 title "Molecular structures, redox properties, and photosubstitution of ruthenium(II) carbonyl complexes of porphycene" @default.
- W2149642984 cites W1964826441 @default.
- W2149642984 cites W1966657347 @default.
- W2149642984 cites W1969046196 @default.
- W2149642984 cites W1969093733 @default.
- W2149642984 cites W1971212705 @default.
- W2149642984 cites W1979594343 @default.
- W2149642984 cites W1984897852 @default.
- W2149642984 cites W1986377600 @default.
- W2149642984 cites W1989123537 @default.
- W2149642984 cites W1993170550 @default.
- W2149642984 cites W1996865479 @default.
- W2149642984 cites W1998363168 @default.
- W2149642984 cites W2000049025 @default.
- W2149642984 cites W2004581578 @default.
- W2149642984 cites W2005067793 @default.
- W2149642984 cites W2012715667 @default.
- W2149642984 cites W2015921558 @default.
- W2149642984 cites W2018630014 @default.
- W2149642984 cites W2019064329 @default.
- W2149642984 cites W2020838849 @default.
- W2149642984 cites W2030540931 @default.
- W2149642984 cites W2031256463 @default.
- W2149642984 cites W2033927234 @default.
- W2149642984 cites W2039374582 @default.
- W2149642984 cites W2041047061 @default.
- W2149642984 cites W2042082202 @default.
- W2149642984 cites W2045809745 @default.
- W2149642984 cites W2046366955 @default.
- W2149642984 cites W2056306467 @default.
- W2149642984 cites W2058774084 @default.
- W2149642984 cites W2061645056 @default.
- W2149642984 cites W2068709655 @default.
- W2149642984 cites W2068858590 @default.
- W2149642984 cites W2069411111 @default.
- W2149642984 cites W2080210139 @default.
- W2149642984 cites W2090873223 @default.
- W2149642984 cites W2114012485 @default.
- W2149642984 cites W2114034966 @default.
- W2149642984 cites W2125328362 @default.
- W2149642984 cites W2126348278 @default.
- W2149642984 cites W2131350133 @default.
- W2149642984 cites W2134968683 @default.
- W2149642984 cites W2135340490 @default.
- W2149642984 cites W2138104420 @default.
- W2149642984 cites W2140047564 @default.
- W2149642984 cites W2164324629 @default.
- W2149642984 cites W2167066468 @default.
- W2149642984 cites W2952128585 @default.
- W2149642984 cites W2952249577 @default.
- W2149642984 cites W4247534712 @default.
- W2149642984 doi "https://doi.org/10.1142/s1088424614501120" @default.
- W2149642984 hasPublicationYear "2015" @default.
- W2149642984 type Work @default.
- W2149642984 sameAs 2149642984 @default.
- W2149642984 citedByCount "4" @default.
- W2149642984 countsByYear W21496429842015 @default.
- W2149642984 countsByYear W21496429842016 @default.
- W2149642984 countsByYear W21496429842017 @default.
- W2149642984 crossrefType "journal-article" @default.
- W2149642984 hasAuthorship W2149642984A5048013176 @default.
- W2149642984 hasAuthorship W2149642984A5052621291 @default.
- W2149642984 hasAuthorship W2149642984A5054986463 @default.
- W2149642984 hasAuthorship W2149642984A5058044716 @default.
- W2149642984 hasConcept C155647269 @default.
- W2149642984 hasConcept C161790260 @default.
- W2149642984 hasConcept C178790620 @default.
- W2149642984 hasConcept C185592680 @default.
- W2149642984 hasConcept C202235601 @default.
- W2149642984 hasConcept C2779480358 @default.
- W2149642984 hasConcept C2779485729 @default.
- W2149642984 hasConcept C540285154 @default.
- W2149642984 hasConcept C555196967 @default.
- W2149642984 hasConcept C55904794 @default.
- W2149642984 hasConcept C71240020 @default.
- W2149642984 hasConcept C75473681 @default.
- W2149642984 hasConceptScore W2149642984C155647269 @default.
- W2149642984 hasConceptScore W2149642984C161790260 @default.
- W2149642984 hasConceptScore W2149642984C178790620 @default.
- W2149642984 hasConceptScore W2149642984C185592680 @default.
- W2149642984 hasConceptScore W2149642984C202235601 @default.
- W2149642984 hasConceptScore W2149642984C2779480358 @default.
- W2149642984 hasConceptScore W2149642984C2779485729 @default.
- W2149642984 hasConceptScore W2149642984C540285154 @default.
- W2149642984 hasConceptScore W2149642984C555196967 @default.
- W2149642984 hasConceptScore W2149642984C55904794 @default.
- W2149642984 hasConceptScore W2149642984C71240020 @default.
- W2149642984 hasConceptScore W2149642984C75473681 @default.
- W2149642984 hasIssue "01-03" @default.
- W2149642984 hasLocation W21496429841 @default.