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- W2149646261 abstract "Abstract Reactions between CoO, ZnCl 2 (or ZnBr 2 ), and molten citric acid (Hcit) led to the formation of two 3d‐3d heterometallic coordination frameworks: [ZnCo(Hcit)Cl] ( 1 ) and [ZnCo(Hcit)Br] ( 2 ). X‐ray structure analyses show that both compounds 1 and 2 crystallize in the monoclinic space group P 2 1 / n [ 1 : a = 5.8699(5) Å, b = 17.7963(13) Å, c = 9.2152(8) Å, β = 106.806(4) °, Z = 4, V = 921.53(13) Å 3 ; 2 : a = 5.909(3) Å, b = 17.798(8) Å, c = 9.302(5) Å, β = 106.374(7) °, Z = 4, V = 938.6(8) Å 3 ]. The structures of the two compounds are almost the same except for the terminal halogen ligand. Both of them are 3D frameworks based on citric acid bridging ligands and a 1D backbone chain built of corner‐shared {CoO 6 } and {ZnO 3 Cl} polyhedra. Photoluminescence and thermal stabilities of the compounds were studied." @default.
- W2149646261 created "2016-06-24" @default.
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- W2149646261 date "2010-10-07" @default.
- W2149646261 modified "2023-10-09" @default.
- W2149646261 title "Synthesis, Crystal Structures, and Characterization of Two 3d-3d Heterometallic Coordination Frameworks: [ZnCo(Hcit)Cl] and [ZnCo(Hcit)Br]" @default.
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- W2149646261 doi "https://doi.org/10.1002/zaac.201000307" @default.
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