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- W2149664586 abstract "The α,β-unsaturated δ-lactone (+)-goniothalamin (18E) and its Z-isomer (18Z), which contain the lactonic moiety of (+)-anamarin (1), have been synthesized from the known 1,2-O-isopropylidene-3-deoxy-α-D-glucofuranose (7). In the key step, methyl 3,5-dideoxy-β-D-glucofuranuronate (15) was treated with benzylidenetriphenylphosphorane in dimethyl sulphoxide to give the E- and Z-β-hydroxy δlactones (17). These were then transformed into the 5,6-dihydro-2-pyrones (18), and also into the aldehyde (20), intended for use in a total synthesis of (+)-anamarin (1)." @default.
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- W2149664586 date "1988-01-01" @default.
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- W2149664586 title "Synthesis of the 5,6-dihydro-2-pyrone moiety of (+)-anamarin" @default.
- W2149664586 doi "https://doi.org/10.1039/p19880002291" @default.
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