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- W2149668170 abstract "Here we report the synthesis of a new crystalline titanium phosphonate material (HTiP-7) having a self-assembled nanostructure and a mesoscopic void space without the aid of any surfactant or templating agent. The material has been synthesized hydrothermally through the reaction between benzene-1,3,5-triphosphonic acid (BTPA) and titanium(IV) isopropoxide at neutral pH at 453 K for 24 h. This hybrid phosphonate material has been thoroughly characterized by powder X-ray diffraction, N2 sorption, HR TEM, FE SEM, TG-DTA, FT IR and UV-Vis diffuse reflectance spectroscopic studies. Two very well-known software packages, REFLEX and CELSIZ unit cell refinement programs, are employed to establish the triclinic crystal phase of this hybrid material (HTiP-7). Very tiny nanocrystals of HTiP-7 self-aggregated to form spherical nanoparticles of dimension ca. 25 nm together with a mesoscopic void space and good BET surface area (255 m2 g−1). The framework is thermally stable up to 650 K. The material showed excellent carrier mobility for photocurrent generation in the presence of a photosensitizer molecule (Rose Bengal). To the best of our knowledge this is the first report of a photon-to-electron energy transfer process over a dye doped titanium phosphonate nanomaterial." @default.
- W2149668170 created "2016-06-24" @default.
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- W2149668170 date "2013-01-01" @default.
- W2149668170 modified "2023-10-11" @default.
- W2149668170 title "Self-assembled titanium phosphonate nanomaterial having a mesoscopic void space and its optoelectronic application" @default.
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- W2149668170 doi "https://doi.org/10.1039/c3dt32744b" @default.
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