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- W2149672263 abstract "An electrophilic attack at the diazo carbon atom is postulated as initiating step in the Lewis acid catalyzed decomposition of diazo compounds. Experimental detection of such primary adducts has now been accomplished with the electronically stabilized (diazomethylene)phosphorane 1, which, for example, gives the salt 2 upon reaction with mercury(II) chloride, and the borate 3 upon reaction with tetrahydrofuran-borane." @default.
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- W2149672263 date "1991-09-01" @default.
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- W2149672263 title "Reactivity of a(Diazomethylene)phosphorane with Alkylating Agents and Lewis Acids; Synthesis of the Firstα-Diazoalkylborates" @default.
- W2149672263 doi "https://doi.org/10.1002/anie.199111541" @default.
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