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- W2149775067 abstract "Electrospray ionization mass spectral analysis of simple dicationic imidazolium prototypes (M·2X) is reported and direct observation was obtained for proton-mediated ion-molecule reactions in the gas phase. The comparative ESI-MS study with heterophanes 1a·2Cl and 3·2Br, the open chain system 5·2Br, and their regiospecific deuterated counterparts 2a·2Cl, 4·2Br and 6·2Br showed that the nature of the frameworks containing two imidazolium subunits modulates their electrospray ionization, changing the stability of the common characteristic peaks: the carbene specie [M − H]+ or [M − D]+ as well as [M]2+ and [M · X]+.Copyright © 2000 John Wiley & Sons, Ltd." @default.
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- W2149775067 date "2000-01-01" @default.
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- W2149775067 title "Imidazolium molecular motifs located on dicationic frameworks. Electrospray mass spectrometric observation of carbenes: imidazolylidenes" @default.
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- W2149775067 doi "https://doi.org/10.1002/1097-0231(20000830)14:16<1443::aid-rcm43>3.0.co;2-h" @default.
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