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- W2149781616 abstract "The geometric structure of tert-butyl isocyanate, (CH3)3CNCO, was determined by gas electron diffraction. The scattering intensities are fitted best with a non-rigid model which possesses a large-amplitude torsional motion of the tert-butyl group around the NC bond and an equilibrium structure with staggered orientation of the tert-butyl group with respect to the NCO group. The nitrogen bond angle [CNC = 137(2)°] is equal to that estimated from rotational constants. It is very similar to CNC angles in methyl and ethyl isocyanate and is not affected by steric interactions." @default.
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- W2149781616 date "1997-09-01" @default.
- W2149781616 modified "2023-09-26" @default.
- W2149781616 title "Tert-butyl isocyanate, a non-rigid molecule" @default.
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- W2149781616 doi "https://doi.org/10.1016/s0022-2860(97)00158-0" @default.
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