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• W2149782025 abstract "Infrared spectra of mono- and dihydrated clusters of 2'-deoxyguanosine (2'-dGs), which are formed by laser desorption combined with supersonic jet-cooling, have been measured by the technique of IR-UV double resonance spectroscopy. The structures of these hydrates are compared with those reported for guanosine (Gs) to elucidate the importance of the 2'-hydroxy group in the hydration. It is shown that monohydrated structures observed for 2'-dGs are similar to those of Gs, indicating no significant influence by the absence of 2'-OH group. For the dihydrated cluster, two structural isomers are identified and assigned to the dihydrates with the guanine moiety is in the keto form, which are consistent with the lowest-energy structures derived from theoretical calculations. Comparison with the results for Gs suggests that the presence of 2'-OH group leads to the stabilization of specific dihydrate structures involving the sugar group." @default.
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• W2149782025 date "2009-01-01" @default.
• W2149782025 modified "2023-10-18" @default.
• W2149782025 title "Hydration structures of 2′-deoxyguanosine studied by IR-UV double resonance spectroscopy: comparison with guanosine" @default.
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• W2149782025 doi "https://doi.org/10.1039/b912684h" @default.
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