FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W2149811152> ?p ?o ?g. }

• W2149811152 endingPage "1160" @default.
• W2149811152 startingPage "1153" @default.
• W2149811152 abstract "Methylviologen-pendant iron porphyrins, in which methylviologen was introduced to the meso-phenyl group through an amido-bridge at either the p- or m-position, were newly synthesized, in expectation that these methylviologen-pendant iron porphyrins would be good functional models of a multi-electron reductase such as nitrite reductase since the methylviologen-pendant can play the role of an electron-trapping and storage unit like the iron–sulfur cluster of the nitrite reductase. These iron porphyrins were successfully applied to the six-electron reduction of nitrobenzene to aniline, which is a model reaction of nitrite reduction to ammonia catalyzed by nitrite reductase. Both p- and m-methylviologen-pendant iron porphyrins give somewhat larger yields of aniline in the reduction of nitrobenzene and much larger yields of p-methoxyaniline in the reduction of p-nitroanisole than does normal iron tetraphenylporphyrin. Though normal iron tetraphenylporphyrin can not catalyze well the reduction of p-nitroanisole in the presence of the dioxygen molecule, these methylviologen-pendant iron porphyrins can catalyze well the reduction of p-nitroanisole and give a considerably larger yield of p-methoxyaniline even in the presence of the dioxygen molecule. These methylviologen-pendant iron porphyrins give a much larger yield of aniline in the reduction of nitrosobenzene and somewhat larger yield of aniline in the reduction of phenylhydroxylamine than does iron tetraphenylporphyrin. m-Methylviologen-pendant iron porphyrin exhibits higher catalytic activity than does the p-pendant one. The role of methylviologen moiety is discussed, based on cyclic voltammograms and UV-VIS spectra of these iron porphyrins." @default.
• W2149811152 created "2016-06-24" @default.
• W2149811152 creator A5003405142 @default.
• W2149811152 creator A5032282169 @default.
• W2149811152 creator A5037755953 @default.
• W2149811152 date "2003-02-10" @default.
• W2149811152 modified "2023-10-16" @default.
• W2149811152 title "Methylviologen-pendant iron porphyrins as models of a reduction enzyme: six-electron reduction of nitrobenzene to anilineElectronic supplementary information (ESI) available: time-courses of reduction, UV-VIS spectral changes, cyclic voltammograms, EPR spectra, conversion and yield percentages for the reduction of p-nitroanisole. See http://www.rsc.org/suppdata/dt/b2/b211125j/" @default.
• W2149811152 cites W1549951942 @default.
• W2149811152 cites W1568462943 @default.
• W2149811152 cites W1584799712 @default.
• W2149811152 cites W1590816720 @default.
• W2149811152 cites W1602084887 @default.
• W2149811152 cites W1970331184 @default.
• W2149811152 cites W1972000448 @default.
• W2149811152 cites W1974803825 @default.
• W2149811152 cites W1975262546 @default.
• W2149811152 cites W1976672362 @default.
• W2149811152 cites W1977950424 @default.
• W2149811152 cites W1985367975 @default.
• W2149811152 cites W1985419411 @default.
• W2149811152 cites W1989031803 @default.
• W2149811152 cites W2001173710 @default.
• W2149811152 cites W2002055474 @default.
• W2149811152 cites W2007930675 @default.
• W2149811152 cites W2008901173 @default.
• W2149811152 cites W2021074065 @default.
• W2149811152 cites W2021454768 @default.
• W2149811152 cites W2025060712 @default.
• W2149811152 cites W2027747227 @default.
• W2149811152 cites W2030650648 @default.
• W2149811152 cites W2034553016 @default.
• W2149811152 cites W2041392522 @default.
• W2149811152 cites W2045031157 @default.
• W2149811152 cites W2045235718 @default.
• W2149811152 cites W2054324010 @default.
• W2149811152 cites W2058027798 @default.
• W2149811152 cites W2060703713 @default.
• W2149811152 cites W2080860726 @default.
• W2149811152 cites W2082715214 @default.
• W2149811152 cites W2082866465 @default.
• W2149811152 cites W2085153350 @default.
• W2149811152 cites W2093156289 @default.
• W2149811152 cites W2095739344 @default.
• W2149811152 cites W2113305715 @default.
• W2149811152 cites W2331358663 @default.
• W2149811152 cites W2336971954 @default.
• W2149811152 cites W2339332223 @default.
• W2149811152 cites W2414317236 @default.
• W2149811152 cites W2137575368 @default.
• W2149811152 cites W2952216240 @default.
• W2149811152 doi "https://doi.org/10.1039/b211125j" @default.
• W2149811152 hasPublicationYear "2003" @default.
• W2149811152 type Work @default.
• W2149811152 sameAs 2149811152 @default.
• W2149811152 citedByCount "10" @default.
• W2149811152 countsByYear W21498111522012 @default.
• W2149811152 countsByYear W21498111522016 @default.
• W2149811152 countsByYear W21498111522018 @default.
• W2149811152 countsByYear W21498111522021 @default.
• W2149811152 countsByYear W21498111522022 @default.
• W2149811152 crossrefType "journal-article" @default.
• W2149811152 hasAuthorship W2149811152A5003405142 @default.
• W2149811152 hasAuthorship W2149811152A5032282169 @default.
• W2149811152 hasAuthorship W2149811152A5037755953 @default.
• W2149811152 hasConcept C161790260 @default.
• W2149811152 hasConcept C178790620 @default.
• W2149811152 hasConcept C179104552 @default.
• W2149811152 hasConcept C185592680 @default.
• W2149811152 hasConcept C2776179834 @default.
• W2149811152 hasConcept C2776384668 @default.
• W2149811152 hasConcept C2778148179 @default.
• W2149811152 hasConcept C2778401137 @default.
• W2149811152 hasConcept C2778478478 @default.
• W2149811152 hasConcept C2779244968 @default.
• W2149811152 hasConcept C2779480358 @default.
• W2149811152 hasConcept C2780809723 @default.
• W2149811152 hasConcept C2781341435 @default.
• W2149811152 hasConcept C75473681 @default.
• W2149811152 hasConceptScore W2149811152C161790260 @default.
• W2149811152 hasConceptScore W2149811152C178790620 @default.
• W2149811152 hasConceptScore W2149811152C179104552 @default.
• W2149811152 hasConceptScore W2149811152C185592680 @default.
• W2149811152 hasConceptScore W2149811152C2776179834 @default.
• W2149811152 hasConceptScore W2149811152C2776384668 @default.
• W2149811152 hasConceptScore W2149811152C2778148179 @default.
• W2149811152 hasConceptScore W2149811152C2778401137 @default.
• W2149811152 hasConceptScore W2149811152C2778478478 @default.
• W2149811152 hasConceptScore W2149811152C2779244968 @default.
• W2149811152 hasConceptScore W2149811152C2779480358 @default.
• W2149811152 hasConceptScore W2149811152C2780809723 @default.
• W2149811152 hasConceptScore W2149811152C2781341435 @default.
• W2149811152 hasConceptScore W2149811152C75473681 @default.
• W2149811152 hasIssue "6" @default.
• W2149811152 hasLocation W21498111521 @default.
• W2149811152 hasOpenAccess W2149811152 @default.
• W2149811152 hasPrimaryLocation W21498111521 @default.
• W2149811152 hasRelatedWork W1981287803 @default.

• next