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• W2149908179 abstract "Abstract The electronic excited states of a meso–meso β–β doubly linked bis‐porphyrin are comprehensively investigated by measuring its circular dichroism (CD) and magnetic circular dichroism (MCD) spectra. The observed spectroscopic properties are rationalized by DFT calculations. The frontier molecular orbitals (MOs) are constructed by the linear combinations of the constituent monomers′ four MOs. Comparison of a theoretical CD spectrum based on time‐dependent DFT (TDDFT) with the experimental spectra resulted in the assignment of the helical conformation of the dimer. This assignment is contrary to the previous assignment based on the point‐dipole approximation (exciton coupling theory)." @default.
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• W2149908179 date "2006-05-31" @default.
• W2149908179 modified "2023-10-17" @default.
• W2149908179 title "Spectroscopic and Theoretical Studies of Optically Active Porphyrin Dimers: A System Uninterpretable by Exciton Coupling Theory" @default.
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• W2149908179 doi "https://doi.org/10.1002/cphc.200500611" @default.
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