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- W215000589 abstract "ABSTRACT By reacting TiCl4 with aluminum, aluminum chloride and benzene at 80°C, a violet, crystallizable complex is rapidly formed, to which we have assigned the empirical formula: Al2TiCl8(C6H5). This complex is active only in the polymerization of ethylene. By its air oxidation, good yields of phenol are formed. Lewis base type compounds react with this complex by fixing a molecule of AlCl3 to them followed by the formation of a crystalline brown complex which precipitates out from the solution. Propylene in the presence of this latter complex yields a crystalline product in which there are present phenyl nuclei, as is shown by its I.R. spectrum." @default.
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- W215000589 date "1967-01-01" @default.
- W215000589 modified "2023-09-27" @default.
- W215000589 title "ORGANOMETALLIC COMPLEXES OBTAINED BY THE REDUCTION OF HYDROCARBON SOLUTIONS OF TITANIUM HALIDES WITH ALUMINUM" @default.
- W215000589 doi "https://doi.org/10.1016/b978-1-4831-9882-8.50053-1" @default.
- W215000589 hasPublicationYear "1967" @default.
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