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- W2150021711 abstract "The synthesis and characterization of a polycarbonate of p-tert-butylcalix[4]arene 4 are reported. It was synthesized by condensation of p-tert-butylcalix[4]arenetetraol derivative 3 with ethyl chloroformate. This new polymer possesses a hydrolyzable backbone and tunable hydrophobic/hydrophilic properties. The experimental results indicate that the polycarbonate was successfully synthesized with average molecular weight overline{M}_{w}, (2.328 times 10^4 g/mol), which was determined by static light scattering method using a Berry plot. The structure of this polymer was determined by IR spectroscopy. The thermal properties were investigated using differential scanning calorimetry (DSC). The degree of crystallinity was measured by means of XRD. The extraction ability of compounds 3 and 4 toward alkali metal cations was studied using conductometry. It was observed that compound 4 had the highest extractability and selectivity toward Na^+." @default.
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- W2150021711 date "2009-01-01" @default.
- W2150021711 modified "2023-10-01" @default.
- W2150021711 title "Synthesis and physical studies of polycarbonate of p-tert-}butylcalix[4]arene: a highly selective receptor for Na^+" @default.
- W2150021711 cites W1603914517 @default.
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- W2150021711 doi "https://doi.org/10.3906/kim-0811-28" @default.
- W2150021711 hasPublicationYear "2009" @default.
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