Matches in SemOpenAlex for { <https://semopenalex.org/work/W2150025619> ?p ?o ?g. }
- W2150025619 endingPage "1003" @default.
- W2150025619 startingPage "994" @default.
- W2150025619 abstract "A series of new manganese phosphonate clusters with unprecedented topologies, [Mn20Na4O12(t-BuPO3)12(O2CMe)16(H2O)12]·5H2O (1), [Mn15O6(MePO3)2(MeCOO)18(H2O)12][MePO3H]2·12H2O (2), and [Mn(t-BuPO3H)2(phen)2]·MeCOOH (3) have been synthesized and characterized. The core of 1 is composed of two folded “butterfly-like” [Mn4(μ3-O)2] units and two trigonal prism [Mn6O6] units connected by four μ3-O, resulting in a twisted oval of twenty homovalent manganese(III) ions. The pentadecanuclear core of complex 2 is mixed-valent, containing six MnIII and nine MnII ions and features six μ4-O and two capping MePO32− anions adopting the binding mode [6.222], forming a rudder-like cage structure with a chiral D3 symmetry. Compound 3 is a manganese(II) phosphonate and features a 1D chain configuration packed by hydrogen bonds and π–π stacking interactions. Magnetic susceptibility measurements reveal that compounds 1, 2 and 3 display antiferromagnetic interactions between the adjacent manganese ions, while the in-phase signal χ′MT and out-of-phase signal χ″M of complex 1 exhibit frequency-dependence below approximately 3 K, but no frequency-dependence is observed in the ac signals of complex 2." @default.
- W2150025619 created "2016-06-24" @default.
- W2150025619 creator A5008138946 @default.
- W2150025619 creator A5027034510 @default.
- W2150025619 creator A5035322817 @default.
- W2150025619 creator A5068299889 @default.
- W2150025619 date "2009-01-01" @default.
- W2150025619 modified "2023-10-12" @default.
- W2150025619 title "Synthesis and characterization of a series of manganese phosphonate complexes with various valences and nuclearity" @default.
- W2150025619 cites W1575131030 @default.
- W2150025619 cites W1948801510 @default.
- W2150025619 cites W1965856637 @default.
- W2150025619 cites W1967160858 @default.
- W2150025619 cites W1971953356 @default.
- W2150025619 cites W1973520650 @default.
- W2150025619 cites W1973721002 @default.
- W2150025619 cites W1974330320 @default.
- W2150025619 cites W1978225379 @default.
- W2150025619 cites W1983862582 @default.
- W2150025619 cites W1988885842 @default.
- W2150025619 cites W1990654323 @default.
- W2150025619 cites W1992427752 @default.
- W2150025619 cites W1994703725 @default.
- W2150025619 cites W1995414833 @default.
- W2150025619 cites W1996816014 @default.
- W2150025619 cites W2000628866 @default.
- W2150025619 cites W2000869573 @default.
- W2150025619 cites W2001164472 @default.
- W2150025619 cites W2005225882 @default.
- W2150025619 cites W2007992316 @default.
- W2150025619 cites W2008090373 @default.
- W2150025619 cites W2008365946 @default.
- W2150025619 cites W2009941338 @default.
- W2150025619 cites W2012973360 @default.
- W2150025619 cites W2013958853 @default.
- W2150025619 cites W2015250459 @default.
- W2150025619 cites W2017679711 @default.
- W2150025619 cites W2018218151 @default.
- W2150025619 cites W2018690340 @default.
- W2150025619 cites W2019810361 @default.
- W2150025619 cites W2023531326 @default.
- W2150025619 cites W2024509898 @default.
- W2150025619 cites W2024569953 @default.
- W2150025619 cites W2025031859 @default.
- W2150025619 cites W2026673235 @default.
- W2150025619 cites W2030638617 @default.
- W2150025619 cites W2032778219 @default.
- W2150025619 cites W2032787413 @default.
- W2150025619 cites W2034800680 @default.
- W2150025619 cites W2036295383 @default.
- W2150025619 cites W2037463866 @default.
- W2150025619 cites W2037625797 @default.
- W2150025619 cites W2039245213 @default.
- W2150025619 cites W2041035248 @default.
- W2150025619 cites W2043510569 @default.
- W2150025619 cites W2044831606 @default.
- W2150025619 cites W2047680396 @default.
- W2150025619 cites W2047891935 @default.
- W2150025619 cites W2049012246 @default.
- W2150025619 cites W2049394062 @default.
- W2150025619 cites W2051596677 @default.
- W2150025619 cites W2052220085 @default.
- W2150025619 cites W2054833860 @default.
- W2150025619 cites W2055046008 @default.
- W2150025619 cites W2055438466 @default.
- W2150025619 cites W2055966463 @default.
- W2150025619 cites W2056449341 @default.
- W2150025619 cites W2057737222 @default.
- W2150025619 cites W2059099486 @default.
- W2150025619 cites W2060657146 @default.
- W2150025619 cites W2066478928 @default.
- W2150025619 cites W2067656423 @default.
- W2150025619 cites W2068553030 @default.
- W2150025619 cites W2069660106 @default.
- W2150025619 cites W2069908783 @default.
- W2150025619 cites W2069974643 @default.
- W2150025619 cites W2071202770 @default.
- W2150025619 cites W2073802644 @default.
- W2150025619 cites W2077835498 @default.
- W2150025619 cites W2078834111 @default.
- W2150025619 cites W2081334931 @default.
- W2150025619 cites W2083046671 @default.
- W2150025619 cites W2084975102 @default.
- W2150025619 cites W2087006788 @default.
- W2150025619 cites W2089655474 @default.
- W2150025619 cites W2089740902 @default.
- W2150025619 cites W2089948920 @default.
- W2150025619 cites W2090688963 @default.
- W2150025619 cites W2091385430 @default.
- W2150025619 cites W2092184984 @default.
- W2150025619 cites W2092520860 @default.
- W2150025619 cites W2093011705 @default.
- W2150025619 cites W2094092050 @default.
- W2150025619 cites W2121239001 @default.
- W2150025619 cites W2122988449 @default.
- W2150025619 cites W2138002693 @default.
- W2150025619 cites W2138465284 @default.
- W2150025619 cites W2139993878 @default.